Transportation Research Record

Natural additives and biopolymers for raw earth construction stabilization – a review

Water scarcity in semi-arid/arid regions is driving the use of salt water in mining operations. A consequence of this shift, is the potentially unheeded effect upon Mine Tailing (MT) management. With existing stabilization/solidification methodologies exhibiting vulnerability to MT toxicity and salinity effects, it is essential to explore the scope for more environmentally durable sustainable alternatives under these conditions. Within this study we investigate the effects of salinity (NaCl, 0-2.5 M) and temperatures associated with arid regions (25 °C, 40 °C), on Locust Bean Gum (LB) biopolymer stabilization of MT exemplar and sand (control) soil systems. A cross-disciplinary 'micro to macro' pipeline is employed, from a Membrane Enabled Bio-mineral Affinity Screen (MEBAS), to Mineral Binding Characterisation (MBC), leading finally to Geotechnical Verification (GV). As predicted by higher Fe2O3 LB binding affinity in saline in the MEBAS studies, LB with 1.25 M NaCl, results in the greatest soil strength in the MT exemplar after 7 days of curing at 40 °C. Under these most challenging conditions for other soil strengthening systems, an overall UCS peak of 5033 kPa is achieved. MBC shows the critical and direct relationship between Fe2O3-LB in saltwater to be 'high-affinity' at the molecular level and 'high-strength' achieved at the geotechnical level. This is attributed to biopolymer binding group's increased availability, with their 'salting-in' as NaCl concentrations rises to 1.25 M and then 'salting-out' at higher concentrations. This study highlights the potential of biopolymers as robust, sustainable, soil stabilization additives in challenging environments. 

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Sustainable biopolymer soil stabilization in saline rich, arid conditions: a ‘micro to macro’ approach

Influence of synthetic waste fibres on drying shrinkage cracking and mechanical properties of adobe materials

In this study the effect of using a biopolymer soil stabilizer on soil stiffness characteristics was investigated. Chitosan is a bio-waste material that is obtained by chemical treatment of chitin (a chemical component of fungi or crustaceans’ shells). Using chitosan solution as a soil stabilizer is based on the assumption that the biopolymer forms temporary bonds with soil particles. What is important is that these bonds are biodegradable, so the product does not leave any harmful waste and has high eco-compatibility. The biopolymer itself is a by-product of many industrial chemical processes, so its application is compliant with the goals of sustainable geotechnical engineering. The effect of chitosan on soil shear strength, permeability or surface erosion has already been investigated in several different studies. In this study specimens of low-cohesive soil stabilized with two different chitosan solutions were subject to cyclic loading (torsional shearing test) and dynamic loading (resonant column) to obtain soil shear modulus G as a function of strain values. It has been shown that chitosan solution added to medium-grained materials improves their shear modulus G substantially (up to 3 times) even for relatively low chitosan concentration solutions (1.5 g of chitosan per 1 kg of dry silica sand). The results obtained in this study and the known chitosan properties suggest that chitosan solutions can be a very effective and eco-friendly short-term stabilizer for temporary geotechnical structures, e.g., working platforms.

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Effect of Chitosan Solution on Low-Cohesive Soil’s Shear Modulus G Determined through Resonant Column and Torsional Shearing Tests

This study aims to check the compatibility of a selection of waste and recycled biopolymers for rammed earth applications in order to replace the more common cement-based stabilization. Five formulations of stabilized rammed earth were prepared with different biopolymers: lignin sulfonate, tannin, sheep wool fibers, citrus pomace and grape-seed flour. The microstructure of the different formulations was characterized by investigating the interactions between earth and stabilizers through mercury intrusion porosimetry (MIP), nitrogen soprtion isotherm, powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). The unconfined compressive strength (UCS) was also evaluated for all stabilized specimens. Three out of five biopolymers were considered suitable as rammed earth stabilizers. The use of wool increased the UCS by 6%, probably thanks to the combined effect of the length of the fibers and the roughness of their surfaces, which gives a contribution in binding clay particles higher than citrus and grape-seed flour. Lignin sulfonate and tannin increased the UCS by 38% and 13%, respectively, suggesting the additives’ ability to fill pores, coat soil grains and form aggregates; this capability is confirmed by the reduction in the specific surface area and the pore volume in the nano- and micropore zones.

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Mechanical and Microstructural Characterization of Rammed Earth Stabilized with Five Biopolymers

The building sector generates around 5-8% of greenhouse gas emissions (GHG)[1] and the disposal of C&D waste at the end-of-life is a high environmental cost. The raw earth is a sustainable construction material with low embedded energy, available locally. It is the most ancient technique of construction, studied in recent years to reduce the environmental life cycle impact of buildings.
Clay is responsible for the earth plastic behaviour and represents the binder that keeps together silt and sand grains. Earth sets through drying without chemical reactions, so it could be reinserted into the nature. At the same time, earthen constructions do not withstand weathering and develop lower mechanical performances compared with those which exploit hydraulic binders. We investigated the possibility of improving these characteristics by stabilizing earthen products with the addition of small amounts of lime preserving clay as eco-friendly binder and the full end-of-life recyclability.
Four earths with different binder properties – two kaolin clays, one illite clay and a smectite – were characterized and analysed at the lab scale. The change of the Atterberg limits on adding lime was determined. The clay modification and potential pozzolanic reactions with lime were measured by X-ray diffraction. Two earths were selected to be tested as plasters, adding sand and lime in order to reduce shrinkage and increase water resistance. Cracking and adhesion tests were run for all mixtures. The results show decreasing performances for all the plasters mixtures stabilized with lime, especially in the presence of an expandable clay fraction. The water resistance is improved for the stabilized mixtures that require less sand to reduce cracking and swelling. Lime is better used as a surface finish and plaster, not as stabilizer, because reacting with clay it increases the plastic limit and raises the water demand to obtain a plastic and workable mixture.

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Evaluation of different raw earthen plasters stabilized with lime for bio-building exploitation

Traditional techniques of construction using natural and locally available materials are nowadays raising the interest of architects and engineers. Clayey soil is widely present in all continents and regions, and where available it is obtained directly from the excavation of foundations, avoiding transportation costs and emissions due to the production of the binder. Moreover, raw earth is recyclable and reusable after the demolition, thanks to the absence of the firing process. The rammed earth technique is based on earth compressed into vertical formworks layer by layer to create a wall. This material owes its strength to the compaction effort and due to its manufacture procedure exhibits layers resembling the geological strata and possessing high architectural value. The hygroscopic properties of rammed earth allow natural control of the indoor humidity, keeping it in the optimal range for human health. Stabilization with lime or cement is the most common procedure to enhance the mechanical and weather resistance at once. This practice compromises the recyclability of the earth and reduces the hygroscopic properties of the material. The use of different natural stabilizers, fibers, and natural polymers by-products of the agriculture and food industry, can offer an alternative that fits the circular economy requirements. The present study analyses the mechanical strength of an Italian earth stabilized with different local waste and recycled materials that do not impair the final recyclability of the rammed earth.

Mechanical Properties of Rammed Earth Stabilized with Local Waste and Recycled Materials

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A. E. Losini

Papers

Natural additives and biopolymers for raw earth construction stabilization – a review

Mechanical and Microstructural Characterization of Rammed Earth Stabilized with Five Biopolymers

Evaluation of different raw earthen plasters stabilized with lime for bio-building exploitation

Mechanical Properties of Rammed Earth Stabilized with Local Waste and Recycled Materials

Biopolymers impact on hygrothermal properties of rammed earth: From material to building scale