A
Adisak Chatupheeraphat
Researcher at RWTH Aachen University
Publications - 13
Citations - 698
Adisak Chatupheeraphat is an academic researcher from RWTH Aachen University. The author has contributed to research in topics: Catalysis & Aryl. The author has an hindex of 11, co-authored 13 publications receiving 573 citations.
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Journal ArticleDOI
Ligand-Controlled Chemoselective C(acyl)-O Bond vs C(aryl)-C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp2)-C(sp3) Cross-Couplings.
Adisak Chatupheeraphat,Hsuan-Hung Liao,Watchara Srimontree,Lin Guo,Yury Minenkov,Albert Poater,Luigi Cavallo,Magnus Rueping,Magnus Rueping +8 more
TL;DR: A ligand-controlled and site-selective nickel catalyzed Suzuki-Miyaura cross-coupling reaction with aromatic esters and alkyl organoboron reagents as coupling partners was developed, providing a facile route for C(sp2)-C(sp3) bond formation in a straightforward fashion by successful suppression of the undesired β-hydride elimination process.
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Asymmetric Brønsted Acid Catalyzed Synthesis of Triarylmethanes-Construction of Communesin and Spiroindoline Scaffolds.
TL;DR: Predictable substitution patterns are found to be the key to the regiodivergent protocols and provide access to diverse communesin and spiroindoline derivatives with high enantioselectivity under mild reaction conditions.
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Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes
TL;DR: An efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described, providing access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.
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Amide to Alkyne Interconversion via a Nickel/Copper-Catalyzed Deamidative Cross-Coupling of Aryl and Alkenyl Amides
TL;DR: A nickel-catalyzed deamidative cross-coupling reaction of amides with terminal alkynes as coupling partners was disclosed and enables a facile route for C(sp2)-C(sp) bond formation in a straightforward and mild fashion.
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Nickel-Catalyzed C−S Bond Formation via Decarbonylative Thioetherification of Esters, Amides and Intramolecular Recombination Fragment Coupling of Thioesters
TL;DR: A nickel catalyzed cross-coupling protocol for the straightforward C-S bond formation has been developed and the utility of this protocol has been demonstrated in a new synthetic protocol of benzothiophene.