A
Adrian C. Whitwood
Researcher at University of York
Publications - 291
Citations - 7761
Adrian C. Whitwood is an academic researcher from University of York. The author has contributed to research in topics: Catalysis & Ligand. The author has an hindex of 45, co-authored 275 publications receiving 6770 citations. Previous affiliations of Adrian C. Whitwood include Heriot-Watt University & University of Strasbourg.
Papers
More filters
Journal ArticleDOI
Spontaneous transfer of parahydrogen derived spin order to pyridine at low magnetic field.
Kevin D. Atkinson,Michael J. Cowley,Paul I. P. Elliott,Simon B. Duckett,Gary G. R. Green,Joaquín López-Serrano,Adrian C. Whitwood +6 more
TL;DR: The degree of signal enhancement in the free substrate is increased by employing electronically rich and sterically encumbered phosphine ligands such as PCy(3), PCy (2)Ph, or P(i)Pr(3) and by optimizing the strength of the magnetic field in which polarization transfer occurs.
Journal ArticleDOI
Contrasting reactivity of fluoropyridines at palladium and platinum: C-F oxidative addition at palladium, P-C and C-F activation at platinum
Naseralla A. Jasim,Robin N. Perutz,Adrian C. Whitwood,Thomas Braun,Joseph Izundu,Beate Neumann,Sascha Rothfeld,H.‐G. Stammler +7 more
TL;DR: The divergent behavior of palladium and platinum is revealed in the reactivity of [M(PR3)2] (M = Pd or Pt; R = Cy or iPr) toward pentafluoropyridine and 2,3,5,6-tetrafluoropeyridine.
Journal ArticleDOI
Improving the Photocatalytic Reduction of CO2 to CO through Immobilisation of a Molecular Re Catalyst on TiO2
Christopher D. Windle,Christopher D. Windle,Ernest Pastor,Anna Reynal,Anna Reynal,Adrian C. Whitwood,Yana Vaynzof,Yana Vaynzof,James R. Durrant,Robin N. Perutz,Erwin Reisner +10 more
TL;DR: ReP–TiO2 compares favourably to previously reported homogeneous systems and is the highest TON reported to date for a CO2-reducing Re photocatalyst under visible light irradiation.
Journal ArticleDOI
Aluminum(salen) Complexes as Catalysts for the Kinetic Resolution of Terminal Epoxides via CO2 Coupling
TL;DR: In this paper, the development of inexpensive and sustainable aluminum(salen) complexes as catalysts for the kinetic resolution of terminal epoxides is described, which is carried out under mild conditions (0 −25 °C and 1 bar of CO2 pressure) in the presence of tetrabutylammonium bromide as co-catalyst in the absence of solvent.
Journal ArticleDOI
Pot, atom and step economic (PASE) synthesis of highly functionalized piperidines: a five-component condensation
TL;DR: In this paper, the diastereoselective pot, atom and step economic (PASE) synthesis of highly functionalized piperidines has been realized, which simply involves mixing methyl acetoacetate, 2 equiv of aldehyde and 2 equaliv of aniline together in the presence of InCl3.