Additive manufacturing of metallic components – Process, structure and properties

Oxygen, one of the most abundant elements on Earth, often forms an undesired interstitial impurity or ceramic phase (such as an oxide particle) in metallic materials. Even when it adds strength, oxygen doping renders metals brittle1–3. Here we show that oxygen can take the form of ordered oxygen complexes, a state in between oxide particles and frequently occurring random interstitials. Unlike traditional interstitial strengthening4,5, such ordered interstitial complexes lead to unprecedented enhancement in both strength and ductility in compositionally complex solid solutions, the so-called high-entropy alloys (HEAs)6–10. The tensile strength is enhanced (by 48.5 ± 1.8 per cent) and ductility is substantially improved (by 95.2 ± 8.1 per cent) when doping a model TiZrHfNb HEA with 2.0 atomic per cent oxygen, thus breaking the long-standing strength–ductility trade-off11. The oxygen complexes are ordered nanoscale regions within the HEA characterized by (O, Zr, Ti)-rich atomic complexes whose formation is promoted by the existence of chemical short-range ordering among some of the substitutional matrix elements in the HEAs. Carbon has been reported to improve strength and ductility simultaneously in face-centred cubic HEAs12, by lowering the stacking fault energy and increasing the lattice friction stress. By contrast, the ordered interstitial complexes described here change the dislocation shear mode from planar slip to wavy slip, and promote double cross-slip and thus dislocation multiplication through the formation of Frank–Read sources (a mechanism explaining the generation of multiple dislocations) during deformation. This ordered interstitial complex-mediated strain-hardening mechanism should be particularly useful in Ti-, Zr- and Hf-containing alloys, in which interstitial elements are highly undesirable owing to their embrittlement effects, and in alloys where tuning the stacking fault energy and exploiting athermal transformations13 do not lead to property enhancement. These results provide insight into the role of interstitial solid solutions and associated ordering strengthening mechanisms in metallic materials. Ordered oxygen complexes in high-entropy alloys enhance both strength and ductility in these compositionally complex solid solutions.

Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes

Laser-based additive manufacturing (LBAM) processes can be utilized to generate functional parts (or prototypes) from the ground-up via layer-wise cladding – providing an opportunity to generate complex-shaped, functionally graded or custom-tailored parts that can be utilized for a variety of engineering applications. Directed Energy Deposition (DED), utilizes a concentrated heat source, which may be a laser or electron beam, with in situ delivery of powder- or wire-shaped material for subsequent melting to accomplish layer-by-layer part fabrication or single-to-multi layer cladding/repair. Direct Laser Deposition (DLD), a form of DED, has been investigated heavily in the last several years as it provides the potential to (i) rapidly prototype metallic parts, (ii) produce complex and customized parts, (iii) clad/repair precious metallic components and (iv) manufacture/repair in remote or logistically weak locations. DLD and Powder Bed Fusion-Laser (PBF-L) are two common LBAM processes for additive metal part fabrication and are currently demonstrating their ability to revolutionize the manufacturing industry; breaking barriers imposed via traditional, ‘subtractive’ metalworking processes. This article provides an overview of the major advancements, challenges and physical attributes related to DLD, and is one of two Parts focused specifically on DLD. Part I (this article) focuses on describing the thermal/fluidic phenomena during the powder-fed DLD process, while Part II focuses on the mechanical properties and microstructure of parts manufactured via DLD. In this current article, a selection of recent research efforts – including methodology, models and experimental results – will be provided in order to educate the reader of the thermal/fluidic processes that occur during DLD, as well as providing important background information relevant to DLD as a whole. The thermal/fluid phenomena inherent to DLD directly influence the solidification heat transfer which thus impacts the part's microstructure and associated thermo-mechanical properties. A thorough understanding of the thermal/fluid aspects inherent to DLD is vital for optimizing the DLD process and ensuring consistent, high-quality parts.

An overview of Direct Laser Deposition for additive manufacturing; Part I: Transport phenomena, modeling and diagnostics

The present study contains a critical review of work on the formation of precipitates and intermetallic phases in dilute precipitation hardening Al–Cu–Mg based alloys with and without Li additions. Although many suggestions for the existence of pre-precipitates in Al–Cu–Mg alloys with a Cu/Mg atomic ratio close to 1 have been made, a critical review reveals that evidence exists for only two truly distinct ones. The precipitation sequence is best represented as: supersaturated solid solution→co-clusters→GPB2/S"→S where clusters are predominantly Cu–Mg co-clusters (also termed GPB or GPB I zones), GPB2/S" is an orthorhombic phase that is coherent with the matrix (probable composition Al10Cu3Mg3) for which both the term GPB2 and S" have been used, and S phase is the equilibrium Al2CuMg phase. GPB2/S" can co-exist with S phase before the completion of the formation of S phase. It is further mostly accepted that the crystal structure of S' (Al2CuMg) is identical to the equilibrium S phase (Al2CuMg). Th...

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Precipitates and intermetallic phases in precipitation hardening Al–Cu–Mg–(Li) based alloys

The mechanical and microstructural properties of 316L stainless steel (SS) fabricated via Direct Laser Deposition (DLD), a laser-based additive manufacturing method, are presented and compared with those of conventionally-built counterparts. Using a Laser Engineered Net Shaping (LENS ® ) DLD system, the time interval between successive layer deposits, or inter-layer/idle time, for fabricating cylindrical specimens vertically-upward was varied by building either one or nine samples per build plate – thus increasing total assembly volume per build. Subsequently, the effect of thermal history, as well as heat treatment, on microstructural (i.e. grain size and morphology) and mechanical (i.e. tensile, compression, and microhardness) properties of DLD parts were investigated. Results indicate that the DLD 316L SS samples produced herein have a higher yield and ultimate tensile strength relative to their cast and wrought forms. Furthermore, the thermal history, microstructural evolution, and mechanical properties of DLD 316L SS are shown to be dependent on the time interval between deposits. Longer local time intervals result in higher cooling rates, leading to finer microstructures, higher/uniform strength and lower elongation to failure. In addition, porosity and less integral metallurgical bonds are found to be more prevalent in locations further upward from the build plate due to reduced laser penetration depths (e.g. previous-layer remelting decreases). Conversely, parts manufactured with shorter time intervals were found to possess a coarser microstructure, lower strength and higher elongation to failure – attributable to lower cooling rates caused by an increased bulk temperature in the part. These results may aid in future design and control of more efficient, constant-power DLD processes – especially with regard to building multiple and/or larger parts; an approach desirable for minimizing small-to-medium lot production times.

Effects of process time interval and heat treatment on the mechanical and microstructural properties of direct laser deposited 316L stainless steel

Because lithium is the least dense elemental metal, materials scientists and engineers have been working for decades to develop a commercially viable aluminum-lithium (Al-Li) alloy that would be even lighter and stiffer than other aluminum alloys. The first two generations of Al-Li alloys tended to suffer from several problems, including poor ductility and fracture toughness; unreliable properties, fatigue and fracture resistance; and unreliable corrosion resistance.
Now, new third generation Al-Li alloys with significantly reduced lithium content and other improvements are promising a revival for Al-Li applications in modern aircraft and aerospace vehicles. Over the last few years, these newer Al-Li alloys have attracted increasing global interest for widespread applications in the aerospace industry largely because of soaring fuel costs and the development of a new generation of civil and military aircraft. This contributed book, featuring many of the top researchers in the field, is the first up-to-date international reference for Al-Li material research, alloy development, structural design and aerospace systems engineering.

Provides a complete treatment of the new generation of low-density AL-Li alloys, including microstructure, mechanical behavoir, processing and applications
Covers the history of earlier generation AL-Li alloys, their basic problems, why they were never widely used, and why the new third generation Al-Li alloys could eventually replace not only traditional aluminum alloys but more expensive composite materials
Contains two full chapters devoted to applications in the aircraft and aerospace fields, where the lighter, stronger Al-Li alloys mean better performing, more fuel-efficient aircraft

Aluminum-Lithium Alloys : Processing, Properties, and Applications

Clad 2 mm thick sheets of Russian 1441 grade Al-Li alloys were welded using a gas tungsten arc welding process (GTAW). Comparisons were made between the weld beads obtained under (i) continuous current (CC), (ii) pulsed current (PC), and (iii) arc oscillation (AO) conditions for their macro- and microstructural details. In the case of CC GTAW, sound welds could be produced only under a narrow range of welding parameters. Centre line cracks, which occurred in CC GTAW welds under certain conditions, were halted by switching to PC or AO conditions while the welding was in progress. Microstructural refinement was significant in the case of PC and AO GTA welding.

Weld microstructure refinement in a 1441 grade aluminium-lithium alloy

Effects of current pulsation frequency on weld bead microstructure, hardness, and tensile properties in AA8090 type aluminium-lithium alloy sheets were studied. It was observed that the structure in the as solidified weld was predominantly columnar in the case of the conventional (i.e. continuous current) gas tungsten arc welding process. The grain structure became finer and more equiaxed with the introduction of current pulsation. Moreover, there was an optimum frequency range over which the grain refinement was a maximum. The same optimum frequency range corresponded with maxima in hardness, ultimate tensile strength, and percentage elongation. Tensile strength increased, in general, after solution treatment and aging (STA). The best combination of tensile properties was achieved for welds deposited under a 6 Hz pulse frequency in the STA condition.

Optimisation of pulse frequency in pulsed current gas tungsten arc welding of aluminium–lithium alloy sheets

Laser engineered net shaping (LENS) and other similar processes facilitate building of parts with freeform shapes by melting and deposition of metallic powders layer by layer. A-priori estimation of the layerwise variations in peak temperature, build dimension, cooling rate, and mechanical property is requisite for successful application of these processes. We present here an integrated approach to estimate these build attributes. A three-dimensional (3-D) heat transfer analysis based on the finite element method is developed to compute the layerwise variation in thermal cycles and melt pool dimensions in the single-line multilayer wall structure of austenitic stainless steel. The computed values of cooling rates during solidification are used to estimate the layerwise variation in cell spacing of the solidified structure. A Hall–Petch like relation using cell size as the structural parameter is used next to estimate the layerwise hardness distribution. The predicted values of layer widths and build heights have depicted fair agreement with the corresponding measured values in actual deposits. The estimated values of layerwise cell spacing and hardness remain underpredicted and overpredicted, respectively. The slight underprediction of the cell spacing is attributed to the possible overestimation of the cooling rates that may have resulted due to the neglect of convective heat transport within the melt pool. The overprediction of the layerwise hardness is certainly due to the underprediction of corresponding cell spacing. The application of Hall–Petch coefficients, which is strictly valid for wrought and annealed grain structures, to estimate the hardness of as-solidified cellular structures may have also contributed to the overprediction of the layerwise hardness.

Estimation of Melt Pool Dimensions, Thermal Cycle, and Hardness Distribution in the Laser-Engineered Net Shaping Process of Austenitic Stainless Steel

Aluminium-lithium alloys hold promise of providing a breakthrough response to the crying need for lightweight alloys for use as structurals in aerospace applications. Considerable worldwide research has gone into developing a range of these alloys over the last three decades. As a result, substantial understanding has been developed of the microstructure-based micromechanisms of strengthening, of fatigue and fracture as well as of anisotropy in mechanical properties. However, these alloys have not yet greatly displaced the conventionally used denser Al alloys on account of their poorer ductility, fracture toughness and low cycle fatigue resistance. This review aims to summarise the work pertaining to study of structure and mechanical properties with a view to indicate the directions that have been and can be pursued to overcome property limitations.

http://www.dunand.northwestern.edu/refs/files/Pe1062.pdf

Amol A. Gokhale

Papers

Aluminum-Lithium Alloys : Processing, Properties, and Applications

Weld microstructure refinement in a 1441 grade aluminium-lithium alloy

Optimisation of pulse frequency in pulsed current gas tungsten arc welding of aluminium–lithium alloy sheets

Estimation of Melt Pool Dimensions, Thermal Cycle, and Hardness Distribution in the Laser-Engineered Net Shaping Process of Austenitic Stainless Steel

Mechanical behaviour of aluminium-lithium alloys