A
André M. Braun
Researcher at Karlsruhe Institute of Technology
Publications - 186
Citations - 11398
André M. Braun is an academic researcher from Karlsruhe Institute of Technology. The author has contributed to research in topics: Singlet oxygen & Aqueous solution. The author has an hindex of 46, co-authored 186 publications receiving 10556 citations. Previous affiliations of André M. Braun include National University of La Plata & Novartis.
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Mineralization of CCl4 by the UVC-photolysis of hydrogen peroxide in the presence of methanol.
TL;DR: A method for a photochemically induced mineralization of CCl4 is described in which use is made of reductive radicals, and carbon dioxide radical anion, CO2(-), an intermediate in the mineralization pathway of methanol, is shown to initiate the mineralized phase by reductive dechlorination.
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Degradation of nitroaromatic compounds by the UV–H2O2 process using polychromatic radiation sources
Fernando Sebastián García Einschlag,Luciano Carlos,Alberto L. Capparelli,André M. Braun,Esther Oliveros +4 more
TL;DR: A standard AOP may be used to evaluate the rate constants of reaction of substrates with hydroxyl radicals under polychromatic as well as under monochromatic irradiation, and optimal amounts of additive may be obtained using only a few parameters as predictive tools.
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Substituent Effects on the Photophysical Properties of Pterin Derivatives in Acidic and Alkaline Aqueous Solutions
Franco M. Cabrerizo,Gabriela Petroselli,Carolina Lorente,Alberto L. Capparelli,Andrés H. Thomas,André M. Braun,Esther Oliveros +6 more
TL;DR: The photophysical properties of acid and basic forms of six compounds of the pterin family and the fluorescence characteristics (spectra, quantum yields, lifetimes) of these compounds have been investigated using the single-photon-counting technique.
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Optimal experimental design and artificial neural networks applied to the photochemically enhanced Fenton reaction
Sabine Göb,Esther Oliveros,Stefan H. Bossmann,André M. Braun,Cláudio Augusto Oller do Nascimento,Roberto Guardani +5 more
TL;DR: An empirical model based on artificial neural networks has been developed for fitting the experimental data obtained in a laboratory batch reactor for the degradation of 2, 4-dimethyl aniline (2,4-xylidine), chosen as a model pollutant, and shows that the process is most sensitive to the concentration of iron(III) salt and temperature, whereas the Concentration of hydrogen peroxide has a minor effect.
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Photochemistry of the singlet oxygen [O2(1Δg)] sensitizer perinaphthenone (phenalenone) in N,N′-dimethylacetamide and 1,4-dioxane
Esther Oliveros,Stefan H. Bossmann,Santi Nonell,Cristina Martí,Gernot Heit,Gabi Tröscher,Annette Neuner,Claudia G. Martínez,André M. Braun +8 more
TL;DR: In this article, it was shown that significant photochemical decomposition of phenalenone occurs under steady-state irradiation in air equilibrated 1,4-dioxane and N,N-dimethylacetamide (DMA), mainly due to hydrogen abstraction from the solvent by its triplet excited state.