A
Andrey Solovyev
Researcher at University of Pittsburgh
Publications - 19
Citations - 1388
Andrey Solovyev is an academic researcher from University of Pittsburgh. The author has contributed to research in topics: Carbene & Boranes. The author has an hindex of 13, co-authored 19 publications receiving 1250 citations. Previous affiliations of Andrey Solovyev include University of St Andrews & University of Illinois at Chicago.
Papers
More filters
Journal ArticleDOI
Synthesis and reactions of N-heterocyclic carbene boranes.
Dennis P. Curran,Andrey Solovyev,Malika Makhlouf Brahmi,Louis Fensterbank,Max Malacria,Emmanuel Lacôte +5 more
TL;DR: This Review provides comprehensive coverage of the synthesis, characterization, and reactions of NHC-boranes.
Journal ArticleDOI
N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical
Shau-Hua Ueng,Andrey Solovyev,Xinting Yuan,Steven J Geib,Louis Fensterbank,Emmanuel Lacôte,Max Malacria,Martin Newcomb,John C. Walton,Dennis P. Curran +9 more
TL;DR: These are the first NHC-boranes with boron-sulfur bonds, and their structures have been secured by spectroscopic and crystallographic means and Spectral analysis suggests that it is a pi-radical analogous to the benzyl radical.
Journal ArticleDOI
EPR Studies of the Generation, Structure, and Reactivity of N-Heterocyclic Carbene Borane Radicals
John C. Walton,Malika Makhlouf Brahmi,Louis Fensterbank,Emmanuel Lacôte,Max Malacria,Qianli Chu,Shau-Hua Ueng,Andrey Solovyev,Dennis P. Curran +8 more
TL;DR: Spectroscopic data and DFT computations demonstrated that the NHC-BH(2)* radicals are planar pi-delocalized species, which is well suited for their reactivity to be tuned by inclusion of different NHC ring units and by appropriate placement of diverse substituents.
Journal ArticleDOI
Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion†
Julien Monot,Andrey Solovyev,Hélène Bonin‐Dubarle,Etienne Derat,Dennis P. Curran,Marc Robert,Louis Fensterbank,Max Malacria,Emmanuel Lacôte +8 more
TL;DR: A lithiated unsubstituted N-heterocyclic carbene (NHC) boryl anion can be generated by reduction, and trapped by electrophiles to provide new substituted NHC boranes, thereby extending the scope of N HC borane chemistry.
Journal ArticleDOI
Substitution reactions at tetracoordinate boron: synthesis of N-heterocyclic carbene boranes with boron-heteroatom bonds.
Andrey Solovyev,Qianli Chu,Steven J. Geib,Louis Fensterbank,Max Malacria,Emmanuel Lacôte,Dennis P. Curran +6 more
TL;DR: Boryl halide, carboxylate and sulfonate complexes of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, which have been prepared from the parent borane dipp-Imd-BH(3) are remarkably stable, and many have been characterized by X-ray crystallography.