E
Etienne Derat
Researcher at University of Paris
Publications - 93
Citations - 3741
Etienne Derat is an academic researcher from University of Paris. The author has contributed to research in topics: Catalysis & Radical. The author has an hindex of 34, co-authored 91 publications receiving 3170 citations. Previous affiliations of Etienne Derat include Pierre-and-Marie-Curie University & Hebrew University of Jerusalem.
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Journal ArticleDOI
Silicates as Latent Alkyl Radical Precursors: Visible-Light Photocatalytic Oxidation of Hypervalent Bis-Catecholato Silicon Compounds
Vincent Corcé,Lise-Marie Chamoreau,Etienne Derat,Jean-Philippe Goddard,Jean-Philippe Goddard,Cyril Ollivier,Louis Fensterbank +6 more
TL;DR: This works introduces hypervalent bis-catecholato silicon compounds as versatile sources of alkyl radicals upon visible-light photocatalysis and proposes a mechanism involving a single-electron transfer from the silicate to the photoactivated iridium complex.
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Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid
Souvik Roy,Bhaskar Sharma,Jacques Pécaut,Philippe Simon,Marc Fontecave,Phong D. Tran,Phong D. Tran,Etienne Derat,Vincent Artero +8 more
TL;DR: A new class of cobalt-based complexes among the most promising CO2-to-formic acid reducing catalysts developed to date is reported, and the role of amine groups for stabilizing key intermediates through hydrogen bonding with water molecules during hydride transfer from the Co center to the CO2 molecule is confirmed.
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Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor
Shau-Hua Ueng,Malika Makhlouf Brahmi,Etienne Derat,Louis Fensterbank,Emmanuel Lacôte,Max Malacria,Dennis P. Curran +6 more
TL;DR: The resulting prediction that NHC borane complexes could be used as radical hydrogen atom donors was verified by radical deoxygenations of xanthates by using either AIBN or triethylborane as initiator.
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Of the Ortho Effect in Palladium/Norbornene-Catalyzed Reactions: A Theoretical Investigation
Giovanni Maestri,Giovanni Maestri,Elena Motti,Nicola Della Ca,Max Malacria,Etienne Derat,Marta Catellani +6 more
TL;DR: The DFT calculations show that, in palladium-catalyzed reaction of aryl halides, not containing ortho substituents, and norbornene, the intermediate palladacycle formed has a good probability to undergo transmetalation, energetically favored over the oxidative addition leading to Pd(IV).
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Non‐Innocent Ligands: New Opportunities in Iron Catalysis
Sébastien Blanchard,Etienne Derat,Marine Desage-El Murr,Louis Fensterbank,Max Malacria,Virginie Mouriès-Mansuy +5 more
TL;DR: In this paper, the chemistry and applications of low-valent iron complexes bearing potentially non-innocent ligands are discussed. But the focus of this review is not on the catalytic properties of these complexes.