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Antony J. Deeming
Researcher at University College London
Publications - 271
Citations - 4058
Antony J. Deeming is an academic researcher from University College London. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 31, co-authored 271 publications receiving 4020 citations.
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Journal ArticleDOI
Two modes of C-H bond activation of tris(2-thienyl)phosphine in trinuclear osmium carbonyl clusters
Mohammed Abdul Mottalib,Shariff E. Kabir,Shariff E. Kabir,Derek A. Tocher,Antony J. Deeming,Ebbe Nordlander +5 more
TL;DR: In this paper, the tris(2-thienyl)phosphine was used to give the phosphine-substituted derivatives [Os 3 (CO) 11 {P(C 4 H 3 S) 3 }] (1, 2, 3, 5, 6 and 7), where the bridging ligand was equatorially coordinated to two osmium atoms.
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Synthesis, structure, and isomerisation of triruthenium and triosmium clusters derived from 3-dimethylaminoprop-1-yne; X-ray crystal structure of [Ru3–H(CO)9(Me2N+C–CCH2)]
Silvio Aime,Domenico Osella,Alejandro J. Arce,Antony J. Deeming,Michael B. Hursthouse,Anita M. R. Galas +5 more
TL;DR: Ru3H(CO)9(Me2NCCCH2) as discussed by the authors was derived by oxidative addition with cleavage of the terminal C-H bond and a 1,3 shift of the NMe2 group.
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Triosmium and triruthenium clusters containing the 4-methylthiazolide ligand: crystal structures of [Os3(µ-H)(CO)10(µ-2,3-η2-CNCMeCHS)], [Os3(µ-H)(CO)9(µ-2,3-η2-CNCMeCHS)(PPh3)] and [Os3(µ-H)(CO)8(µ-2,3-η2-CNCMeCHS)(PPh3)2]
Kazi A. Azam,Rahima Dilshad,Shariff E. Kabir,Khodeja Khatoon,Lutfun Nessa,Md. Mukhlesur Rahman,Edward Rosenberg,Michael B. Hursthouse,K. M. Abdul Malik,Antony J. Deeming +9 more
TL;DR: In this article, the same authors showed that the reaction of [Os3(H)2(CO)8(µ-2,3-η2]-graphic omitted] with 4-methylthiazole in the presence of sodium-benzophenone at 67 °C gave [Ru3(C)2.5] and [Ru4(C]2.7] respectively.
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Trapping of an unstable tautomer of indole by ortho-metallation at triosmium clusters
TL;DR: Indole was reacted with [OS3(CO)12] in an attempt to prepare the analogue of the C,C-bonded clusters [Os3H2(μ3-CCCHCHN R)(CO)9] (1; R = H or Me) formed by direct double oxidative additions of pyrrole or N-methylpyrrole at [Os 3(CO), 12].
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Cleavage of phosphorus–phenyl and phosphorus-2-pyridyl bonds in the reactions of mixed phenyl-(2-pyridyl) phosphines with [Ru3(CO)12]
TL;DR: In this paper, it was shown that the 2-pyridyl group that has migrated bridges two ruthenium atoms with no Ru-Ru bond between them and that the di(2pyrideyl) phosphido ligand is triply bridging with one nitrogen co-ordinated and one free.