A
Armando Gennaro
Researcher at University of Padua
Publications - 173
Citations - 10091
Armando Gennaro is an academic researcher from University of Padua. The author has contributed to research in topics: Atom-transfer radical-polymerization & Catalysis. The author has an hindex of 52, co-authored 167 publications receiving 8788 citations. Previous affiliations of Armando Gennaro include Australian National University & Paris Diderot University.
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Electrochemically mediated atom transfer radical polymerization
Krzysztof Matyjaszewski,Nicola Bortolamei,Andrew J. D. Magenau,Armando Gennaro,Abdirisak Ahmed Isse +4 more
TL;DR: In this article, the reduction of an ATRP catalyst, C 11 Br 2 /Me 6 TREN, is shown to be an efficient process to mediate and execute an AT RP.
Journal ArticleDOI
Absolute Potential of the Standard Hydrogen Electrode and the Problem of Interconversion of Potentials in Different Solvents
TL;DR: The absolute potential of the standard hydrogen electrode, SHE, was calculated on the basis of a thermodynamic cycle involving H(2(g)) atomization, ionization of H((g))* to H(( g))(+), and hydration of H(+) to obtain a SHE value based on the chemical potential.
Journal ArticleDOI
Mechanism of Photoinduced Metal-Free Atom Transfer Radical Polymerization: Experimental and Computational Studies.
Xiangcheng Pan,Cheng Fang,Marco Fantin,Marco Fantin,Nikhil Malhotra,Woong Young So,Linda A. Peteanu,Abdirisak Ahmed Isse,Armando Gennaro,Peng Liu,Krzysztof Matyjaszewski +10 more
TL;DR: A deeper understanding of the chemical processes of metal-free ATRP is provided that can aid the design of better catalytic systems and elucidates several important common pathways involved in synthetically useful organic reactions catalyzed by photoredox catalysts.
Journal ArticleDOI
Reversible-Deactivation Radical Polymerization in the Presence of Metallic Copper. A Critical Assessment of the SARA ATRP and SET-LRP Mechanisms
Dominik Konkolewicz,Yu Wang,Mingjiang Zhong,Pawel Krys,Abdirisak Ahmed Isse,Armando Gennaro,Krzysztof Matyjaszewski +6 more
TL;DR: The mechanism of reversible deactivation radical polymerization (RDRP) in the presence of Cu0 has been extensively studied in the literature as mentioned in this paper, with a variety of mechanisms proposed.
Journal ArticleDOI
Electrochemically mediated atom transfer radical polymerization (eATRP)
Paweł Chmielarz,Paweł Chmielarz,Marco Fantin,Marco Fantin,Sangwoo Park,Abdirisak Ahmed Isse,Armando Gennaro,Andrew J. D. Magenau,Andrzej Sobkowiak,Krzysztof Matyjaszewski +9 more
TL;DR: In this paper, a review of electrochemically mediated atom transfer radical polymerization (eATRP) setup is discussed in detail, together with the advantages and limitations of this technique.