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Ashley C. Stowe

Researcher at Oak Ridge National Laboratory

Publications -  76
Citations -  2053

Ashley C. Stowe is an academic researcher from Oak Ridge National Laboratory. The author has contributed to research in topics: Neutron detection & Neutron. The author has an hindex of 19, co-authored 76 publications receiving 1907 citations. Previous affiliations of Ashley C. Stowe include University of Bremen & Vanderbilt University.

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In situ solid state 11B MAS-NMR studies of the thermal decomposition of ammonia borane: mechanistic studies of the hydrogen release pathways from a solid state hydrogen storage material

TL;DR: A mechanistic model for the induction, nucleation and growth for AB decomposition leading to formation of hydrogen is proposed, which yields a mobile phase of AB caused by disruption of the dihydrogen bonds and nucleation that yields reactive DADB from the mobile AB.
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Structure, Electrochemistry, and Magnetism of the Iron(III)-Substituted Keggin Dimer, [Fe6(OH)3(A-α-GeW9O34(OH)3)2]11-

TL;DR: Remarkable efficiency of 1 in the electrocatalytic reduction of nitrite, nitric oxide, and nitrate is demonstrated and EPR studies confirm that the ground state is indeed diamagnetic, since the EPR signal intensity steadily decreases without any line broadening as the temperature is lowered and becomes unobservable below about 50 K.
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Sandwich-type germanotungstates: structure and magnetic properties of the dimeric polyoxoanions [M4(H2O)2(GeW9O34)2]12 - (M = Mn2+, Cu2+, Zn2+, Cd2+).

TL;DR: X-ray single-crystal analyses of the novel dimeric germanotungstates and W-NMR studies of the diamagnetic Zn and Cd derivatives indicate that the solid-state polyoxoanion structures are preserved in solution.
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Coherent Carbon Cryogel−Ammonia Borane Nanocomposites for H2 Storage

TL;DR: Findings include a merged two-step hydrogen release reaction with an appreciable reduction in the dehydrogenation temperature to <90 degrees C as well as the suppression of borazine release.
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Structure and Magnetism of the Tetra-Copper(II)-Substituted Heteropolyanion [Cu4K2(H2O)8(α-AsW9O33)2]8-†

TL;DR: In this article, the authors synthesize and characterize a novel heteropolyanion [Cu4K2(H2O)8(α-AsW9O33)2]8- (1) by IR spectroscopy, elemental analysis, and magnetic studies.