Electrolytes and interphases in Li-ion batteries and beyond.

4.4. Pd on Modified Silica 159 4.5. Pd on Clay and Other Inorganic Materials 159 5. Stille, Fukuyama, and Negishi Reactions 159 5.1. Stille Reactions 159 5.1.1. Pd on Carbon (Pd/C) 159 5.1.2. Palladium on KF/Al2O3 159 5.1.3. Pd on Modified Silica (SiO2/TEG/Pd) 159 5.2. Fukuyama Reactions 159 5.2.1. Pd on Carbon (Pd/C) 159 5.2.2. Pd(OH)2 on Carbon (Perlman’s Catalyst) 160 5.3. Pd/C-Catalyzed Negishi Reactions 160 6. Ullmann-Type Coupling Reactions 161 6.1. Pd/C-Catalyzed Aryl−Aryl Coupling 161 6.2. Pd/C-Catalyzed Homocoupling of Vinyl Halides 162

https://www.chem.ccu.edu.tw/~joyce/referance/ericyang/Chem.%20Rev/Chem.%20Rev.%202007,%20107,%20133-173.pdf

Carbon-Carbon Coupling Reactions Catalyzed by Heterogeneous Palladium Catalysts

Thermal runaway caused fire and explosion of lithium ion battery

Thermal runaway mechanism of lithium ion battery for electric vehicles: A review

Recent applications of the Suzuki–Miyaura cross-coupling reaction in organic synthesis

A new method for obtaining cross‐linked second‐order nonlinear optical polymer by photochemical reaction has been described. An active dye was processed and poled in a photoreactive polymer in a manner similar to doped polymer system, and photo‐cross‐linked in the poled phase by ultraviolet irradiation. The dye doped (20% by weight) cross‐linked polymer has a nonlinear optical coefficient d33 of 5.1 pm/V at 1.540 μm and shows no relaxation after being subjected to thermal treatment at 60 °C for 0.5 h.

Cross‐linked stable second‐order nonlinear optical polymer by photochemical reaction

Thermal runaway inhibitors for lithium battery electrolytes

An approach for the enzyme-mediated in-situ synthesis of polymers in two dimensions on a Langmuir trough surface is reported. Horseradish peroxidase-mediated polymerization of monomer mixtures of unsubstituted and long alkyl chain substituted phenols and aromatic amines at the air-water interface was demonstrated. The use of the Langmuir trough to organize and orient the reactants results in improved control of monomer reactivity and orientation in the resulting polymer compared to the polymer synthesized in bulk solvent. In turn, this enhanced control results in improved processability because of reduced chain branching. Good thermal stability and significant electronic and optical properties of the ordered polymer were demonstrated. This interfacial polymerization procedure creates opportunities in the development of improved materials for applications in biology, medicine, and microelectronics.

Enzymic Mediated Synthesis of Conjugated Polymers at the Langmuir Trough Air-Water Interface

New low temperature electrolytes with thermal runaway inhibition for lithium-ion rechargeable batteries

The third‐order nonlinear optical properties of multilayered films containing 23% by weight of an axially modified silicon phthalocyanine derivative have been measured by degenerate four‐wave mixing at 532 nm with 70 ps full width at half maximum pulses. The average χ(3)of the films measured at (1.33±0.15) ×10−11 esu using CS2 as a standard and the cubic hyperpolarizability 〈γ〉 was calculated at (1.97±0.22)×10−32esu. The degenerate four‐wave mixing signal profile indicates that the films have a response time better than 70 ps.

Braja K. Mandal

Papers

Cross‐linked stable second‐order nonlinear optical polymer by photochemical reaction

Thermal runaway inhibitors for lithium battery electrolytes

Enzymic Mediated Synthesis of Conjugated Polymers at the Langmuir Trough Air-Water Interface

New low temperature electrolytes with thermal runaway inhibition for lithium-ion rechargeable batteries

Third‐order nonlinear optical response in a multilayered phthalocyanine composite