C
Carlo Floriani
Researcher at University of Lausanne
Publications - 203
Citations - 5543
Carlo Floriani is an academic researcher from University of Lausanne. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 39, co-authored 203 publications receiving 5381 citations. Previous affiliations of Carlo Floriani include Columbia University.
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Complexes derived from the reaction of manganese(III) Schiff base complexes and hexacyanoferrate(III): Syntheses, multidimensional network structures, and magnetic properties
TL;DR: In this paper, a two-dimensional network layer structure was analyzed and magnetic measurements showed its metamagnetic behavior, where the ferromagnetic interaction operates within each layer and the antiferromagnetic interactions between the layers.
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Enantioselective Reduction of Ketones by Polymethylhydrosiloxane in the Presence of Chiral Zinc Catalysts
TL;DR: In this article, an enantioselective reduction of ketones, particularly acetophenones, by polymethylhydrosiloxane (PMHS) to the corresponding secondary alcohols can be achieved with high yields and enantiomeric excesses up to 88% in the presence of chiral zinc catalysts.
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Synthesis, Crystal Structure, and Magnetic Properties of a Ferrimagnetic Layered Compound [NEt4][Mn(5-Cl-salen)]2[Fe(CN)6] (NEt4 = Tetraethylammonium, 5-Cl-salen = N,N‘-Ethylenebis((5-chlorosalicylidene)aminato))
TL;DR: In this paper, the discrete trinuclear complex (NEt4) was synthesized in the monoclinic space group P21/c with cell dimensions of a = 13.104, b = 12.861, c = 15.526, and β = 105.98.
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Assembling Bi-, Tri- and Pentanuclear Complexes into Extended Structures Using a Desolvation Reaction: Synthesis, Structure, and Magnetic Properties of Manganese(III)-Schiff-Base-Hexacyanoferrate Polymeric Compounds and Their Derived Extended Structures
Hitoshi Miyasaka,Hidenori Ieda,Naohide Matsumoto,Nazzareno Re,Raffaella Crescenzi,Carlo Floriani +5 more
TL;DR: In this article, a binuclear binuclear unit was characterized by X-ray analysis. But the complexity of the Binuclear Binuclear Unit (BINU) was not characterized.
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Dinitrogen Rearranging over a Metal−Oxo Surface and Cleaving to Nitride: From the End-On to the Side-On Bonding Mode, to the Stepwise Cleavage of the N⋮N Bonds Assisted by NbIII-calix[4]arene
Alessandro Caselli,Euro Solari,Rosario Scopelliti,Carlo Floriani,Nazzareno Re,and Corrado Rizzoli,A. Chiesi-Villa +6 more
TL;DR: In this paper, four-electron reduction of dinitrogen has been achieved in the reaction of N2 with [p-But-calix[4]-(O)4}2Nb2(μ-M)2] (M = Li, 3, M = Na, 4; M = K, 5), which contain a very reactive NbNb unit.