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Cezmi Kayan

Researcher at Dicle University

Publications -  45
Citations -  532

Cezmi Kayan is an academic researcher from Dicle University. The author has contributed to research in topics: Catalysis & Transfer hydrogenation. The author has an hindex of 15, co-authored 40 publications receiving 454 citations.

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Synthesis of new aminophosphine complexes and their catalytic activities in C–C coupling reactions

TL;DR: In this article, two new aminophosphines, benzyl-N(Ph2P)(2) and 2-picolyl-N (Ph2p)(2), have been synthesized and characterised by NMR, IR spectroscopy and microanalysis.
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New chiral phosphinite ligands with C2‐symmetric axis and their possible applications in Ru‐catalyzed asymmetric transfer hydrogenation

TL;DR: In this paper, the chiral ligands N,N′-bis-[(1R)-1-ethyl-2-O-(diphenylphosphinite)ethyl]ethanediamide, 1, and the corresponding ruthenium complexes 3 and 4 were prepared and their structures were elucidated by a combination of multinuclear NMR spectroscopy, IR and elemental analysis.
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Rhodium-catalyzed transfer hydrogenation with functionalized bis(phosphino)amine ligands

TL;DR: A series of cationic mononuclear rhodium(I) complexes with the P-N-P ligands have been prepared starting from the complex [Rh(cod) 2 ]BF 4, and structural elucidation of the complexes was carried out by elemental analyses, IR and multinuclear NMR spectroscopic data as discussed by the authors.
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Transfer hydrogenation of ketones catalyzed by new rhodium and iridium complexes of aminophosphine containing cyclohexyl moiety and photosensing behaviors of rhodium and iridium based devices

TL;DR: In this article, the reaction of [Rh( μ -Cl)(cod)] 2 and Ir( η 5 -C 5 Me 5 )( μ-Cl)Cl] 2 with aminophosphine ligands Cy 2 PNHCH 2 -C 4 H 3 X (X: O; S) gave a range of new monodendate complexes, which were characterized by analytical and spectroscopic methods.
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Synthesis and characterization of ether-derivatized aminophosphines and their application in C-C coupling reactions

TL;DR: In this article, the bis(phosphino)amine ligands (Ph2P)2N-C6H3-R, where R = 3,5-OMe (1), 2,5-, 2,4-OME (2), 3,4-, or 3, 4-, were prepd. via aminolysis of the corresponding dimethoxyanilines with 2 equiv.