Journal ArticleDOI
Synthesis of new aminophosphine complexes and their catalytic activities in C–C coupling reactions
Nermin Biricik,Feyyaz Durap,Cezmi Kayan,Bahattin Gümgüm,Nevin Gürbüz,İsmail Özdemir,Wee Han Ang,Zhaofu Fei,Rosario Scopelliti +8 more
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TLDR
In this article, two new aminophosphines, benzyl-N(Ph2P)(2) and 2-picolyl-N (Ph2p)(2), have been synthesized and characterised by NMR, IR spectroscopy and microanalysis.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 2008-08-01. It has received 58 citations till now. The article focuses on the topics: Palladium & Coupling reaction.read more
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Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands.
TL;DR: The aim of this review is to highlight how the diversity generated by N-substitution in the well-known short-bite ligand bis(diphenylphosphino)amine (DPPA) allows a fine-tuning of the ligand properties and offers a considerable scope for tailoring the properties and applications of their corresponding metal complexes.
Journal ArticleDOI
Aminophosphines: their chemistry and role as ligands and synthons
TL;DR: The chemistry of simple acyclic aminophosphines (synthesis, characterization, reactivity and applications) is covered and particular focus is given to their ability to form chalcogenides along with their role played as ligands in coordination chemistry and as synthons in inorganic heterocyclic chemistry as mentioned in this paper.
Journal ArticleDOI
Synthesis, structural characterization, and electrochemical properties of dinuclear Ni/Mn model complexes for the active site of [NiFe]-hydrogenases.
TL;DR: Four new dinuclear Ni/Mn model complexes have been prepared via the four separated step-reactions involving six new precursors and have been structurally characterized, while model complexes 7 and 9 have been found to be catalysts for HOAc proton reduction to hydrogen under CV conditions.
Journal ArticleDOI
Syntheses, Structures, and Catalytic Ethylene Oligomerization Behaviors of Bis(phosphanyl)aminenickel(II) Complexes Containing N‐Functionalized Pendant Groups
TL;DR: Several N-functionalized bisphosphanylamine ligands respectively containing benzyl, furfuryl, thiophene-2-methyl, and 2-picolyl groups (1a-e) were synthesized and characterized as mentioned in this paper.
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Analysis of the water extract of waste papaya bark ash and its implications as an in situ base in the ligand-free recyclable Suzuki–Miyaura coupling reaction
TL;DR: In this article, the conversion of waste papaya-bark to ash-water extract via low-temperature combustion, and its utilisation as an efficient and environmentally friendly in situ basic medium for the Suzuki-Miyaura cross-coupling reaction at room temperature are reported.
References
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Journal ArticleDOI
Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
TL;DR: In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
Journal ArticleDOI
SIRPOW.92 – a program for automatic solution of crystal structures by direct methods optimized for powder data
Angela Altomare,Giovanni Luca Cascarano,C. Giacovazzo,Antonietta Guagliardi,Maria Cristina Burla,Giampiero Polidori,Mercedes Camalli +6 more
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Chemistry of the elements
TL;DR: In this article, the origins of the elements, isotopes and atomic weights Chemical periodicity and the periodic table were discussed, including the following elements: Hydrogen Lithium, sodium, potassium, rubidium, caesium and francium Beryllium, magnesium, calcium, strontium, barium and radium Boron Aluminium, gallium, indium and thallium Carbon Silicon Germanium, tin and lead Nitrogen Phosphorus Arsenic, antimony and bismuth Oxygen Sulfur Selenium, tellurium
Journal ArticleDOI
SIR92 – a program for automatic solution of crystal structures by direct methods
Angela Altomare,Giovanni Luca Cascarano,C. Giacovazzo,Antonietta Guagliardi,Maria Cristina Burla,Giampiero Polidori,Mercedes Camalli +6 more
Journal ArticleDOI
An empirical method for correcting diffractometer data for absorption effects
N. Walker,David I. Stuart +1 more
TL;DR: In this article, a Fourier series in the polar angles of the incident and diffracted beam paths is used to model an absorption surface for the difference between the observed and calculated structure factors.