Showing papers in "Inorganica Chimica Acta in 2013"

TL;DR: The compound [Ru3(CO)12] was used as a precursor for the preparation of ruthenium nanoparticles of a typical size of 1 µm as mentioned in this paper.

TL;DR: Ru(III) and Pt(II) complexes have been synthesized as antibacterial agents, aiming to enhance the biological activity of sulfamethazine drug against resistance development of some organisms.

TL;DR: In this paper, a combined experimental and computational study of novel mixed ligand Cu(II), Ni(II) and Co-II complexes of 2-(1-(2-phenyl-hydrazono)-propan-2-ylidene)hydrazine-carbothioamide (TPHP) and 1,10-phenanthroline (1,10Phen) have been synthesized.

TL;DR: In this paper, the authors show that MIL-100(Cr)-EN is very promising as a water sorption material, e.g., for heat-transformation applications.

TL;DR: In this paper, the effect of intermolecular interactions and correlation in tetranuclear complexes has been investigated and the results further support that judicious choice of harmonious mixed ligands provides the means to create a rich variety of new isolated individual {M4O4} cubic system and allows a systematic magnetic study.

TL;DR: In this paper, the results of X-ray crystallographic studies of PdCl2(AsPh3)2 and 2-hydroxy-1-naphthaldehyde-4(N)-methylthiosemicarbazone [H2-(Sal-ptsc)] (H2L1) were carried out in ethanol/dichloromethane medium.

TL;DR: In this article, a review of the coordination polymers that can be attained with ligands containing the sulphur-based dithiocarbamate (dtc), DTC, DTC-carboxylate and xanthate functional groups is given.

TL;DR: In this paper, the bis-carbene Ag(I) complexes (3 and 4) were synthesized from 4 via the technique of transmetallation, and the molecular structure of Ag complexes was elucidated by X-ray diffraction studies.

TL;DR: In this paper, dipicolylamine (DPA) was shown to be highly select for Zn2+ over Cd2+ and other cations such as Hg2+, Fe2+, Mn2+, and Ca2+.

TL;DR: In this paper, a novel N-donor bridging receptor R : 4,4′-methanediylbis(2-ethyl-5-methyl-1 H -imidazole) has been synthesized from 2ethyl-4-methyl 1 H-imidaze and formaldehyde in the presence of potassium hydroxide.

TL;DR: Palladium nanoparticles of a definite shape (spherical) and dimension (8−14 and 16−20nm) were prepared employing two water soluble lignin samples as both reducing and stabilizing agent in definitely green experimental conditions, namely aqueous solution, aerobic conditions, moderate temperature, short times as mentioned in this paper.

TL;DR: In this article, a non-planar Zn-R/S-L2 complex is characterized by IR, UV-Vis, 1H NMR, mass spectrometry, circular dichroism (CD), and polarimetry.

TL;DR: In this article, a new hybrid compound (C6H9N2)2HgCl4 was synthesized and characterized by a single-crystal X-ray diffraction, thermal analysis, IR, Raman and impedance spectroscopy.

TL;DR: New cationic heteroleptic Ln(III) complexes with acetylacetonate and bis(5-(pyridine-2-yl)-1,2,4-triazol-3-yl)propane basis are synthesized by various means, including single crystal X-ray diffraction analysis.

TL;DR: In this article, the kinetics and mechanism of redox reaction between gold(III) chloride complex ions and lascorbic acid in the aqueous solution have been carried out using spectrophotometric technique.

TL;DR: Two homodinuclear copper(II) end-on bis(μ-acetato/μ-nitrato) bridged complexes with two NNO donor ligands are reported in this paper.

TL;DR: C-H activation of inert hydrocarbons: New cobalt, nickel and copper complexes with the tripodal 4N ligand Me6TREN (tris[2-(dimethylamino)ethyl]amine and related compounds are tested as homogeneous catalysts for the partial oxidation of cyclohexane and adamantane in the presence of the sacrificial oxidant m-chloroperbenzoic acid.

TL;DR: In this article, six square planar Ni(II) complexes of 3,3-dialkyl/aryl-1-benzoylthiourea derivatives have been synthesized and characterized by elemental analyses, and electronic, FT-IR and NMR spectroscopic techniques.

TL;DR: In this paper, a review of the formation processes of metal macrocyclic chelate complexes into biopolymer polypeptide medium (BPIM) using self-assembly reactions is presented.

TL;DR: Three copper(II) complexes, [Cu2L2(μ1,1-NCO)(NCO)] (1), [cu2L 2(μ 1,3-NCS)(NCS)] (2) and [CuL(μ 5-dca)]n·nH2O (3), have been prepared and characterized by elemental analysis, IR and UV-Vis spectroscopy, single crystal X-ray diffraction studies and by cyclic voltammetry as discussed by the authors.

TL;DR: A tridentate NNO donor base ligand HL [HL: C5H4NCH=NNHCONH2] was obtained by condensation of pyridine 2-carbaldehyde with semicarbazide.

TL;DR: Inhibition of the enzyme thioredoxin reductase (TrxR) was confirmed for the gold derivatives containing dppm and dppb bridging ligands and indicated a preference for the shorter bridgingligand.

TL;DR: These values represent improved cytotoxicity against both cell lines, especially for the silver complexes 2a and 2b, which are not only more active than SBC3 but also exhibit in the case of 2b a 7 times higher biological activity than cisplatin.

TL;DR: In this paper, a tridentate N,N,O-donor ligand was synthesized from a tripartite N, N,O donor ligand and three new coordination complexes, [Cu(L)(nic)(NO3)]·CH3OH·0.63H2O (1), 2[cu(L), NO3],·1 CH3OH (2), and [Cu (L-NO2)(NO2),(NO3), (3) were characterized by elemental analyses and spectroscopic methods.

TL;DR: Two active complexes Ru-1 and Ru-2 were identified to effectively inhibit BEL-7402, HeLa, MCF-7 and MG-63 cells growth and induced apoptosis in BEL- 7402 cells through the mitochondrial pathway.

TL;DR: In this article, a one-pot synthesis of three new ferrocene incorporated selenoureas was reported, namely; 1-(2-fluorobenzoyl)-3-(4-ferrocenyl-3-methylphenyl)selenourea (MeP2F), 1-(3-fluorsenoyl), 3-methyl-4-fricenyl aniline (3-M-Aniline), and MeP4F, by the reaction of corresponding carboxylic acid chlorides with potassium se

TL;DR: Methane sulfonicacid hydrazide (a sulfonamide compound, msh : CH 3 SO 2 NHNH 2 ) derivatives: salicylaldehydemethanesulfonylhydrazone (salmsh), salmsh, 2-hydroxyacetophenonemethane methylonyl hydrazone, afmsh and o-vanmsh have been synthesized.

TL;DR: In this article, quaternized 2Q, 3Q and 4Q phthalocyanines with calf thymus (CT) DNA were investigated by UV-Vis, fluorescence spectrophotometric methods and gel electrophoresis.

TL;DR: In this article, aroylhydrazone ligands derived from new bis(hydroxybenzylidene)-substituted terephthalo and oxalo hydrazides were prepared and characterized by FT-IR and NMR spectroscopy.

TL;DR: In this paper, the synthesis and structural characterization of seven heterodinuclear complexes are reported, where the structures of all the complexes consist of diphenoxo-bridged heterometallic cores in which CuII metal ion is trapped in N2O2 compartment of the Schiff-base ligand, while the second metal ion was present in the larger and open O4 [O(phenoxo)2O(methoxy)2] compartment.