Chao Zou

TL;DR: A two-step synthesis strategy has led to a unique layered polyoxometalate-Mn(III)-metalloporphyrin-based hybrid material that demonstrates remarkable capability for scavenging of dyes and for heterogeneous selective oxidation of alkylbenzenes with excellent product yields and 100% selectivity.

TL;DR: A luminescent MOF material containing 1D nanotube channels is synthesized, and a dye@MOF platform is developed to realize the probing of different VOMs by tuning the energy transfer efficiency between two different emissions.

TL;DR: The results indicate that ZJ U-18 is much superior to ZJU-19, ZjU-20, and homogeneous molecular MnCl-Me(8)OCPP, exhibiting highly efficient and selective oxidation of ethylbenzene to acetophenone in quantitative >99% yield and a turnover number of 8076 after 48 h.

TL;DR: The postmodification of the MONT can be easily operated by unmarking the imidazolium moieties in the channel walls, which was conducted as a highly active heterogeneous catalyst for Suzuki-Miyaura and Heck coupling reactions, hydrogenation of olefins and nitrobenzene, while the constituent elements are less efficient for these reactions under the same conditions.

TL;DR: The immobilization of the photoactive Sn-porphyrins in the channel walls lets the MOF present remarkable photocatalytic activities for the oxygenation of phenol and sulfides, resulting in excellent yields and remarkable selectivity in heterogeneous phases.