C
Christopher C. Cummins
Researcher at Massachusetts Institute of Technology
Publications - 362
Citations - 13478
Christopher C. Cummins is an academic researcher from Massachusetts Institute of Technology. The author has contributed to research in topics: Triple bond & Reactivity (chemistry). The author has an hindex of 62, co-authored 342 publications receiving 12073 citations. Previous affiliations of Christopher C. Cummins include University of Miami & Harvard University.
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Journal ArticleDOI
Facile Synthesis of AsP3
TL;DR: Physical properties and spectroscopic characterization data for AsP3 are described, and its structure was determined as a ligand in a coordination complex, representing an attractive starting point for any synthesis in which the target molecule or material contains an exact 1:3 ratio of arsenic to phosphorus.
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Formation of cyclo-E4(2-) units (E4 =P4, As4, AsP3) by a complex with a Cr-Cr quintuple bond.
Christoph Schwarzmaier,Awal Noor,Germund Glatz,Manfred Zabel,Alexey Y. Timoshkin,Brandi M. Cossairt,Christopher C. Cummins,Rhett Kempe,Manfred Scheer +8 more
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Four-Coordinate Molybdenum Chalcogenide Complexes Relevant to Nitrous Oxide N−N Bond Cleavage by Three-Coordinate Molybdenum(III): Synthesis, Characterization, Reactivity, and Thermochemistry
Adam R. Johnson,William M. Davis,Christopher C. Cummins,Scafford Serron,Steven P. Nolan,Djamaladdin G. Musaev,Keiji Morokuma +6 more
TL;DR: In this paper, the terminal chalcogenide complexes Mo(E)(N[R]Ar)3 (R = C(CD3)2CH3, Ar = 3,5-C6H3Me2), where E = O, S, Se, and Te, were prepared by reaction of the three-coordinate complex Mo(N[r] Ar)3 with ONC5H5, S8 or SC2H4, Se and Te/PEt3 in respective yields of 72, 63, 80, and 73%.
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Synthesis and characterization of P2N3 −: An aromatic ion composed of phosphorus and nitrogen
TL;DR: The synthesis of the diphosphatriazolate anion is reported, a rare example of a planar aromatic inorganic species and its aromatic character was confirmed by NICS and QTAIM methods.
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Terminal, Anionic Carbide, Nitride, and Phosphide Transition‐Metal Complexes as Synthetic Entries to Low‐Coordinate Phosphorus Derivatives
TL;DR: Anionic terminal one-atom nitride, phosphide, and carbide complexes are excellent starting materials for the synthesis of ligands containing low-coordinate phosphorus centers in the protecting coordination sphere of the metal complex.