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Christopher C. Cummins

Researcher at Massachusetts Institute of Technology

Publications -  362
Citations -  13478

Christopher C. Cummins is an academic researcher from Massachusetts Institute of Technology. The author has contributed to research in topics: Triple bond & Reactivity (chemistry). The author has an hindex of 62, co-authored 342 publications receiving 12073 citations. Previous affiliations of Christopher C. Cummins include University of Miami & Harvard University.

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Book ChapterDOI

A Cross-Linguistic Study on Information Backgrounding and Presupposition Projection

TL;DR: Amaral et al. as mentioned in this paper investigated the distinction between two classes of presupposition triggers posited in the theoretical literature, namely that between lexical and resolution triggers, and found that native speakers exhibit the same tendencies with respect to the addressability of foregrounded vs backgrounded content in coherent question-answer pairs.
Journal ArticleDOI

Heterobimetallic reductive cross-coupling of benzonitrile with carbon dioxide, pyridine, and benzophenone.

TL;DR: Heterobimetallic radical cross-coupling reactions between the benzonitrile adduct of the molybdenum( III) complex Mo(N[t-Bu]Ar)3 and titanium(III) complexes with carbon dioxide, pyridine, and benzophenone and the selective cross-C bond formation takes place with dearomatization.
Journal ArticleDOI

Rationalizing the different products in the reaction of N2 with three-coordinate MoL3 complexes.

TL;DR: In the absence of steric strain, the formation of the metal-metal bonded dimer, Mo2L6, is the most exothermic pathway but this reaction shows the greatest sensitivity to ligand size, with the energetically and kinetically favoured product being the nitride complex L3Mo-N.
Journal ArticleDOI

Synthesis and Reversible Reductive Coupling of Cationic, Dinitrogen-Derived Diazoalkane Complexes

TL;DR: Both electrochemical investigations and quantum chemical calculations are used to describe the odd-electron complex 4-RC(6)H(4)C(H)NNMo(N[t-Bu]Ar)(3), 1-R, that is an intermediate in the formation of [1-R](2).
Journal ArticleDOI

Synthetic and Spectroscopic Investigations Enabled by Modular Synthesis of Molecular Phosphaalkyne Precursors

TL;DR: A series of dibenzo-7-phosphanorbornadiene compounds, Ph3PC(R)PA, are reported to be capable of thermal fragmentation to generate alkyl-substituted phosphaalkynes (RC≡P) concomitant with triphenylphosphine and anthracene.