C
Colette Boskovic
Researcher at University of Melbourne
Publications - 107
Citations - 4372
Colette Boskovic is an academic researcher from University of Melbourne. The author has contributed to research in topics: Magnetic susceptibility & Magnetization. The author has an hindex of 34, co-authored 99 publications receiving 3869 citations. Previous affiliations of Colette Boskovic include Indiana University & University of Bern.
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Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligands
TL;DR: In this paper, the authors investigated the thermodynamic basis of valence tautomeric (VT) transition in a metal complex with a redox-active organic ligand, and showed that a number of factors additional to the redoxactive metal-ligand unit influence the manifestation of the VT transition.
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Single-Molecule Magnets: A New Family of Mn12 Clusters of Formula [Mn12O8X4(O2CPh)8L6]
Colette Boskovic,Euan K. Brechin,William E. Streib,Kirsten Folting,John C. Bollinger,David N. Hendrickson,George Christou +6 more
TL;DR: In this paper, a magnetochemical investigation of complex 2 reveals an S = 6 or 7 ground state and frequency-dependent out-of-phase signals in ac susceptibility studies that establish it as a new class of single-molecule magnet.
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Quantum Tunneling of Magnetization in a New [Mn18]2+ Single-Molecule Magnet with S = 13
Euan K. Brechin,Colette Boskovic,Wolfgang Wernsdorfer,Jae Yoo,Akira Yamaguchi,E C Sanudo,T R Concolino,and Arnold L. Rheingold,H. Ishimoto,David N. Hendrickson,George Christou +10 more
TL;DR: Complex 1 is both the largest spin and highest nuclearity SMM to exhibit QTM, indicative of quantum tunneling of magnetization (QTM) between the lowest energy Ms = +/-13 levels of the S = 13 state.
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Terbium polyoxometalate organic complexes: correlation of structure with luminescence properties.
TL;DR: Comparison of this octanuclear TbIII complex of 2-picolinate and tungstoarsenate ligands with a dinuclear relative reveals the role of the organic ligands as chromophores, identifies the luminescent Tb centers, and determines the relationship between POM coordination mode and luminescence quenching.
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Single-Molecule Magnets: Ligand-Induced Core Distortion and Multiple Jahn−Teller Isomerism in [Mn12O12(O2CMe)8(O2PPh2)8(H2O)4]
TL;DR: In this paper, the Mn12Ac single-molecule magnet has been converted for the first time into a form that contains non-carboxylate ligands using diphenylphosphinic acid.