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Cunyuan Zhao

Researcher at Sun Yat-sen University

Publications -  115
Citations -  2714

Cunyuan Zhao is an academic researcher from Sun Yat-sen University. The author has contributed to research in topics: Catalysis & Carbenoid. The author has an hindex of 23, co-authored 110 publications receiving 2264 citations. Previous affiliations of Cunyuan Zhao include Northwest Normal University & University of Science and Technology of China.

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Intermolecular electronic coupling of organic units for efficient persistent room-temperature phosphorescence

TL;DR: A new mechanism for pRTP is presented, based on combining the advantages of different excited‐state configurations in coupled intermolecular units, which may be applicable to a wide range of organic molecules.
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Key mechanistic features of Ni-catalyzed C-H/C-O biaryl coupling of azoles and naphthalen-2-yl pivalates.

TL;DR: The modified catalytic cycle for the Ni(cod)(dcype)-catalyzed C-H/C-O coupling of benzoxazole and naphthalen-2-yl pivalate is proposed and emerging mechanistic knowledge was validated.
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Graphene oxide with improved electrical conductivity for supercapacitor electrodes

TL;DR: In this paper, a few-layer graphene (FLG) sheets of high electrical conductivity have been synthesized by a multi-step intercalation and reduction method, and the electrical conductivities of the as-synthesized FLG is measured to be ∼3.2 × 10 4 ǫ s −1, comparable to that of pristine graphite.
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A DFT study on the mechanism of Rh2(II,II)-catalyzed intramolecular amidation of carbamates.

TL;DR: The potential-energy surfaces of the reactions of dirhodium tetracarboxylate (Rh2(II,II) catalyzed nitrene (NR) insertion into C-H bonds were examined by a DFT computational study.
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cis-β-Bis(carbonyl) Ruthenium−Salen Complexes: X-ray Crystal Structures and Remarkable Catalytic Properties toward Asymmetric Intramolecular Alkene Cyclopropanation

TL;DR: The intramolecular cyclopropanation from the cis-beta-carbene species is the most favorable pathway and features an early transition state and an asynchronous concerted [2 + 1] addition mechanism.