D
D. Yu. Antonov
Researcher at A. N. Nesmeyanov Institute of Organoelement Compounds
Publications - 13
Citations - 71
D. Yu. Antonov is an academic researcher from A. N. Nesmeyanov Institute of Organoelement Compounds. The author has contributed to research in topics: Nucleophilic addition & Butyllithium. The author has an hindex of 4, co-authored 13 publications receiving 69 citations.
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Journal ArticleDOI
A novel class of bidentate ligands with a conformationally flexible biphenyl unit built into a planar chiral [2.2]paracyclophane backbone
TL;DR: In this paper, a planar chiral bidentate aryl[2.2]paracyclophane ligands were synthesized using Suzuki cross-coupling.
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Coordination chemistry of mercury-containing anticrowns. Synthesis and structure of an unusual discrete, double-decker sandwich complex of cyclic trimeric perfluoro-o-phenylenemercury with an aromatic hydrocarbon
I. A. Tikhonova,Dmitry A. Gribanyov,K. I. Tugashov,F. M. Dolgushin,A. S. Peregudov,D. Yu. Antonov,V.I. Rosenberg,Vladimir B. Shur +7 more
TL;DR: In this article, a double-decker sandwich complex of the three-mercury anticrown with [2.2]paracyclophane (PCP) was synthesized.
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Synthesis of (2.2)paracyclophane-pseudo-ortho-dicarboxylic acid
TL;DR: In this article, an efficient three-step synthesis of [2.2]paracyclophane-pseudo-ortho-dicarboxylic acid by dibromination was developed.
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Stereoselective synthesis of cis-4,7-disubstituted 4,7-dihydroxy-4,7-dihydro[2.2]paracyclophanes
N. V. Vorontsova,Valeria I. Rozenberg,E. V. Vorontsov,D. Yu. Antonov,Zoya A. Starikova,Yu. N. Bubnov +5 more
TL;DR: In this article, the nucleophilic addition of butyllithium, phenyllithia, methyllithiam, and triallylborane to [2.2]paracyclophane-4,7-quinone (1) proceeded regio- and stereospecifically to give the corresponding cis-4-7-disubstituted 4,7dihydroxy-4.7-diagrams with the endo orientation of the hydroxy groups, and the structures of quinone 1 and diols
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Influence of transannular interaction over absorption and fluorescent properties of [2.2] paracyclophane and its phenyl derivatives
TL;DR: In this article, a significant bathochromic shift of the fluorescent and long-wavelength absorption bands of [2.2] paracyclophane comparing to corresponding bands of alkyl-benzenes is due to a strong transannular interaction, resulting in formation of a new excited state of lower energy.