Journal ArticleDOI
Coordination chemistry of mercury-containing anticrowns. Synthesis and structure of an unusual discrete, double-decker sandwich complex of cyclic trimeric perfluoro-o-phenylenemercury with an aromatic hydrocarbon
I. A. Tikhonova,Dmitry A. Gribanyov,K. I. Tugashov,F. M. Dolgushin,A. S. Peregudov,D. Yu. Antonov,V.I. Rosenberg,Vladimir B. Shur +7 more
Reads0
Chats0
TLDR
In this article, a double-decker sandwich complex of the three-mercury anticrown with [2.2]paracyclophane (PCP) was synthesized.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 2010-07-01. It has received 18 citations till now. The article focuses on the topics: Coordination complex & Aromatic hydrocarbon.read more
Citations
More filters
Journal ArticleDOI
Discrete and Extended Supersandwich Structures Based on Weak Interactions between Phosphorus and Mercury
Martin Fleischmann,Claudia Heindl,Michael Seidl,Gábor Balázs,Alexander V. Virovets,Eugenia V. Peresypkina,Mitsukimi Tsunoda,François P. Gabbaï,Manfred Scheer +8 more
TL;DR: Adducts with polymeric or discrete supersandwich structures form from mixtures of the trinuclear mercury complex with the triple-decker complex in the solid state.
Journal ArticleDOI
Molecular curvature tradeoffs: Bending a planar trimercury unit over bowl-shaped polyaromatic hydrocarbons
Alexander S. Filatov,Allison K. Greene,Edward A. Jackson,Lawrence T. Scott,Marina A. Petrukhina +4 more
TL;DR: In this article, the reactions of three bowl-shaped polyaromatic hydrocarbons, namely, 1,2,5,6-tetramethylcorannulene (C24H18), dibenzo[a,g]CORANNULENE (C28H14), and bicorannulenyl (C40H18) with the highly electrophilic trimercury complex, resulted in the formation of 1D extended binary π-adducts.
Journal ArticleDOI
Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules
Kirill I. Tugashov,Dmitry Gribanyov,Fedor M. Dolgushin,Alexander F. Smol'yakov,Alexander S. Peregudov,Marija Kh. Minacheva,Irina A Tikhonova,Vladimir B. Shur +7 more
TL;DR: In this paper, a double-decker sandwich structure for the three-mercury anticrown (o-C6F4Hg)3 (1) with [PPh4][BF4] in methanol at room temperature leads to the formation of a fluoride complex with a wedge-shaped geometry.
Journal ArticleDOI
Synthesis, crystal structure, and optical characteristics of [Pd2Hg4Cl6{Te(DMB)}6]·2DMF, [HgClTe(DMB)]4, and the ring-forming cluster [Pd12(TePh)24]·2DMF
Barbara Tirloni,Ernesto Schulz Lang,Gelson Manzoni de Oliveira,Paulo Piquini,Manfredo Hörner +4 more
TL;DR: In this article, the core of compound 1 was analyzed by first principles DFT and the results confirm the existence of two systems 3c−4e−, in which the two TeII atoms act as bridging ligands.
Journal ArticleDOI
Supramolecular adducts based on weak interactions between the trimeric Lewis acid complex (perfluoro-ortho-phenylene)mercury and polypnictogen complexes
TL;DR: In all cases, the reaction products show very weak interactions between the En ligand complexes and the Lewis acid 1, as evidenced by their highly dynamic behaviour in solution and the formation of adducts in the solid state showing HgE contacts below the respective sum of the van der Waals radii.
References
More filters
Book
Encyclopedia of supramolecular chemistry
TL;DR: Artificial Enzymes o DNA Nanotechnology o Drug Design o Imaging and Targeting o Natural Strategies for the Molecular Engineer o pi-pi interactions: theory and scope oSelf-Assembly in Biochemistry o Vibrational Spectroscopy.
Journal ArticleDOI
Recognition of Electron-Donating Guests by Carborane-Supported Multidentate Macrocyclic Lewis Acid Hosts: Mercuracarborand Chemistry
Journal ArticleDOI
The van der Waals radius of mercury
Allan J. Canty,Glen B. Deacon +1 more
TL;DR: In this paper, the van der Waals radius of mercury compounds has been shown to be in the range 1.7-2.0 A. A general value for the radius should lie at the conservative end of the range, which corresponds to Grdenic's largely neglected upper limit for any form of bonding, is proposed.
Journal ArticleDOI
Multidentate carborane-containing Lewis acids and their chemistry: mercuracarborands
TL;DR: Macrocyclic Lewis acidic hosts with structures incorporating electron-withdrawing icosahedral carboranes and electrophilic mercury centers bind a variety of electron-rich guests as mentioned in this paper.
Journal ArticleDOI
Ab initio studies of the dimers (HgH2)2 and (HgMe2)2. Metallophilic attraction and the van der Waals radii of mercury
Pekka Pyykkö,Michal Straka +1 more
TL;DR: In this paper, the authors used the dispersion and electrostatic multipole components to determine the energy of the "metallophilic" attraction between two Hg(II) compounds.
Related Papers (5)
Lewis Acidic Behavior of Fluorinated Organomercurials
Darstellung und Eigenschaften von Tetrafluorphthalsäure-Derivaten
Peter Sartori,Alfred Golloch +1 more