D
Diana L. Anderson
Researcher at Brigham Young University
Publications - 3
Citations - 74
Diana L. Anderson is an academic researcher from Brigham Young University. The author has contributed to research in topics: Allylic rearrangement & Nucleophile. The author has an hindex of 3, co-authored 3 publications receiving 64 citations.
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Journal ArticleDOI
Origin of Fast Catalysis in Allylic Amination Reactions Catalyzed by Pd–Ti Heterobimetallic Complexes
Whitney K. Walker,Benjamin M. Kay,Scott A. Michaelis,Diana L. Anderson,Stacey J. Smith,Daniel H. Ess,David J. Michaelis +6 more
TL;DR: Computational and experimental studies demonstrate that the Pd-Ti interaction induces and is responsible for significantly lower barriers and faster catalysis for allylic aminations.
Journal ArticleDOI
Allylic aminations with hindered secondary amine nucleophiles catalyzed by heterobimetallic Pd-Ti complexes.
TL;DR: Three titanium-containing ligands are shown to assemble active catalysts in situ and enable catalysis at room temperature, and a variety of sterically bulky secondary amines are efficiently allylated in high yields with as little as 1 mol % palladium catalyst.
Journal ArticleDOI
Allylic Aminations with Hindered Secondary Amine Nucleophiles Catalyzed by Heterobimetallic Pd—Ti Complexes.
TL;DR: In this article, three titanium-containing ligands are shown to assemble active catalysts in situ and enable catalysis at room temperature, and a variety of sterically bulky secondary amines are efficiently allylated in high yields with as little as 1 mol % palladium catalyst.