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Eberhardt Herdtweck

Researcher at Ludwig Maximilian University of Munich

Publications -  280
Citations -  7852

Eberhardt Herdtweck is an academic researcher from Ludwig Maximilian University of Munich. The author has contributed to research in topics: Crystal structure & Rhenium. The author has an hindex of 49, co-authored 280 publications receiving 7641 citations. Previous affiliations of Eberhardt Herdtweck include University of Siena & Chemical Research Center of the Hungarian Academy of Sciences.

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Octahedral bipyridine and bipyrimidine dioxomolybdenum(VI) complexes: characterization, application in catalytic epoxidation, and density functional mechanistic study.

TL;DR: Experimental results are supported by theoretical calculations, which show that the attack of TBHP at the Mo center through the X-O-N face is energetically favored and the TBHP hydrogen atom is transferred to a terminal oxygen of the Mo=O moiety.
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Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen: CXXVI. Heterocyclen-Carbene als phosphananaloge Liganden in Metallkomplexen

TL;DR: In this article, it was shown that dicarbenes derived from imidazole and triazole, as generated from the corresponding azolium precursor salts, smoothly react with simple metal carbonyls such as M(CO)6 (M  Cr, Mo, W), Fe( CO)5, and Ni(CO 2L2L2) to give the substitution products M( CO 5L, Fe 4L, Ni 2L 2, and Ni 3L 2.
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Mechanistic insights into heterogeneous zinc dicarboxylates and theoretical considerations for CO2-epoxide copolymerization.

TL;DR: The results imply that the widely discussed bimetallic mechanism (for homogeneous catalysts) is in place for heterogeneous zinc dicarboxylates as well.