E
Eckhard Bill
Researcher at Max Planck Society
Publications - 414
Citations - 17937
Eckhard Bill is an academic researcher from Max Planck Society. The author has contributed to research in topics: Electron paramagnetic resonance & Ligand. The author has an hindex of 69, co-authored 396 publications receiving 16392 citations. Previous affiliations of Eckhard Bill include University of Lübeck & University of Otago.
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Electronic Structure of Bis(o-iminobenzosemiquinonato)metal Complexes (Cu, Ni, Pd). The Art of Establishing Physical Oxidation States in Transition-Metal Complexes Containing Radical Ligands
Phalguni Chaudhuri,Cláudio Nazari Verani,Eckhard Bill,Eberhard Bothe,Thomas Weyhermüller,Karl Wieghardt +5 more
TL;DR: The ligand 2-anilino-4,6-di-tert-butylphenol and its 2-(3,5-dichloroanilino)-4,4-dimethyl-1,4,7-triazacyclononane analogue react in CH(3)CN or CH( 3)OH solutions with divalent transition metal ions in the presence of air and triethylamine.
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Weakly ferromagnetic ordered mesoporous Co₃O₄ synthesized by nanocasting from vinyl-functionalized cubic Ia3d mesoporous silica
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Mononuclear (nitrido)iron(V) and (oxo)iron(IV) complexes via photolysis of [(cyclam-acetato)FeIII(N3)]+ and ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in water/acetone mixtures.
TL;DR: In this article, a spin-Hamiltonian analysis of the magnetic Mossbauer spectra is consistent with an FeV ion (d3, S = 3/2), and a minor product containing high-valent iron (d6, S= 0) complexes 1red and 2ared have been prepared by electrochemical and chemical methods.
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Neutral bis(alpha-iminopyridine)metal complexes of the first-row transition ions (Cr, Mn, Fe, Co, Ni, Zn) and their monocationic analogues: mixed valency involving a redox noninnocent ligand system.
TL;DR: The cationic nickel complex is exceptional in this series in that it does not exhibit any ligand mixed valency, and its electronic structure is consistent with two neutral ligands (L)0 and a monovalent metal center or [(L)2Ni(THF)][B(ArF)4].
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Molecular and electronic structure of four- and five-coordinate cobalt complexes containing two o-phenylenediamine- or two o-aminophenol-type ligands at various oxidation levels: an experimental, density functional, and correlated ab initio study.
Eckhard Bill,Eberhard Bothe,Phalguni Chaudhuri,Krzysztof Chłopek,Diran Herebian,Swarnalatha Kokatam,Kallol Ray,Thomas Weyhermüller,Frank Neese,Karl Wieghardt +9 more
TL;DR: It is shown that the corresponding nickel complexes 8 and 9 contain a low-spin nickel(II) ion regardless of the oxidation level of the ligand, whereas for the corresponding cobalt complexes the situation is more complicated.