E
Elliot P. Farney
Researcher at University of Wisconsin-Madison
Publications - 12
Citations - 533
Elliot P. Farney is an academic researcher from University of Wisconsin-Madison. The author has contributed to research in topics: Immunotherapy & Cancer research. The author has an hindex of 5, co-authored 8 publications receiving 412 citations. Previous affiliations of Elliot P. Farney include California Institute of Technology.
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Journal ArticleDOI
Visible-light sensitization of vinyl azides by transition-metal photocatalysis.
Elliot P. Farney,Tehshik P. Yoon +1 more
TL;DR: The ability to use low-energy visible light instead of UV in the photochemical activation of azides avoids competitive photodecomposition processes that have long been a significant limitation on the synthetic use of these reactions.
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Photocatalytic [2 + 2] Cycloadditions of Enones with Cleavable Redox Auxiliaries
TL;DR: Cleavage of the imidazolyl auxiliary from the cycloadducts affords cyclobutane carboxamides, esters, thioesters, and acids that would not be accessible from direct cycloaddition of the corresponding unsaturated carbonyl compounds.
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Spin-Selective Generation of Triplet Nitrenes: Olefin Aziridination through Visible-Light Photosensitization of Azidoformates.
TL;DR: It is shown that visible-light-activated transition-metal complexes can be triplet sensitizers that selectively produce aziridines through the spin-selective photogeneration of triplet nitrenes from azidoformates.
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Total Synthesis of (+)-Pleuromutilin
TL;DR: The chemistry described here will enable efforts to prepare new mutilin antibiotics and was also used to prepare (+)-12-epi-pleuromutilin.
Journal ArticleDOI
Discovery and Elucidation of Counteranion Dependence in Photoredox Catalysis.
Elliot P. Farney,Steven J. Chapman,Wesley B. Swords,Marco D. Torelli,Robert J. Hamers,Tehshik P. Yoon +5 more
TL;DR: It is demonstrated thatcounteranion effects exert a surprising, dramatic impact on the rate of a representative photocatalytic radical cation Diels-Alder reaction and the importance of counteranion identity as a variable in the design and optimization of photoredox transformations is demonstrated.