E
Emmanuelle Schulz
Researcher at Université Paris-Saclay
Publications - 161
Citations - 9336
Emmanuelle Schulz is an academic researcher from Université Paris-Saclay. The author has contributed to research in topics: Catalysis & Enantioselective synthesis. The author has an hindex of 37, co-authored 158 publications receiving 8688 citations. Previous affiliations of Emmanuelle Schulz include Claude Bernard University Lyon 1 & Russian Academy of Sciences.
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Journal ArticleDOI
Harnessing the Lewis Acidity of HFIP through its Cooperation with a Calcium(II) Salt: Application to the Aza‐Piancatelli Reaction
David Lebœuf,Lucile Marin,Bastien Michelet,Alejandro Perez-Luna,Régis Guillot,Emmanuelle Schulz,Vincent Gandon,Vincent Gandon +7 more
TL;DR: It is proposed that HFIP is, in fact, acting as a Lewis acid and that its acidity can be enhanced when combined with a calcium(II) salt.
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Intramolecular enantioselective hydroamination catalyzed by rare earth binaphthylamides
TL;DR: In this article, a new family of structurally defined heterobimetallic rare earth lithium ate complexes based on N-substituted binaphthylamido ligands was discovered that promoted the hydroamination/cyclization of aminoolefins with up to 87% ee.
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Recent progress in asymmetric heterogeneous catalysis: use of polymer-supported catalysts
Christine Saluzzo,Rob ter Halle,François Touchard,Fabienne Fache,Emmanuelle Schulz,Marc Lemaire +5 more
TL;DR: In this paper, the asymmetric heterogeneous catalytic reduction of carbonyl bonds by hydrogen transfer reduction or hydrogenation by means of molecular hydrogen as well as asymmetric allylic substitution of allylic acetates are reported.
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Catalytic, Enantioselective Intramolecular Hydroamination of Primary Amines Tethered to Di- and Trisubstituted Alkenes
Yulia Chapurina,Yulia Chapurina,Houssein Ibrahim,Régis Guillot,Emilie Kolodziej,Emilie Kolodziej,Jacqueline Collin,Jacqueline Collin,Alexander A. Trifonov,Emmanuelle Schulz,Emmanuelle Schulz,Jérôme Hannedouche,Jérôme Hannedouche +12 more
TL;DR: These chiral heteroleptic complexes demonstrate the ability to promote the cyclization of amine-tethered trisubstituted alkenes in up to 55% ee, as the first report of the formation of enantioenriched quaternary centers by an hydroamination reaction.
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Well-defined and easily accessible yttrium complexes for enantioselective cyclisation of amines tethered to 1,2-di-substituted alkenes
Yulia Chapurina,Jérôme Hannedouche,Jacqueline Collin,Régis Guillot,Emmanuelle Schulz,Alexander A. Trifonov +5 more
TL;DR: A straightforward in situ preparation of new chiral amido alkyl ate yttrium complexes catalysed the enantioselective cyclisation of 1,2-dialkyl-substituted aminopentenes in up to 77% ee, a significant value for this challenging transformation.