System Identification I

: The unpolarized absorption and circular dichroism spectra of the fundamental vibrational transitions of the chiral molecule, 4-methyl-2-oxetanone, are calculated ab initio. Harmonic force fields are obtained using Density Functional Theory (DFT), MP2, and SCF methodologies and a 5S4P2D/3S2P (TZ2P) basis set. DFT calculations use the Local Spin Density Approximation (LSDA), BLYP, and Becke3LYP (B3LYP) density functionals. Mid-IR spectra predicted using LSDA, BLYP, and B3LYP force fields are of significantly different quality, the B3LYP force field yielding spectra in clearly superior, and overall excellent, agreement with experiment. The MP2 force field yields spectra in slightly worse agreement with experiment than the B3LYP force field. The SCF force field yields spectra in poor agreement with experiment.The basis set dependence of B3LYP force fields is also explored: the 6-31G* and TZ2P basis sets give very similar results while the 3-21G basis set yields spectra in substantially worse agreements with experiment. jg

Ab initio calculation of vibrational absorption and circular dichroism spectra using density functional force fields

The scope of this review is the nature and dynamics of the singlet excited electronic states created in nucleic acids and their constituents by UV light. Interest in the UV photochemistry of nucleic acids has long been the motivation for photophysical studies of the excited states, because these states are at the beginning of the complex chain of events that culminates in photodamage. UV-induced damage to DNA has profound biological consequences, including photocarcinogenesis, a growing human health problem.1-3 Sunlight, which is essential for life on earth, contains significant amounts of harmful UV (λ < 400 nm) radiation. These solar UV photons constitute one of the most ubiquitous and potent environmental carcinogens. This extraterrestrial threat is impressive for its long history; photodamage is as old as life itself. The genomic information encoded by these biopolymers has been under photochemical attack for billions of years. It is not surprising then that the excited states of the nucleic acid bases (see Chart 1), the most important UV chromophores of nucleic acids, are highly stable to photochemical decay, perhaps as a result of selection pressure during a long period of molecular evolution. This photostability is due to remarkably rapid decay pathways for electronic energy, which are only now coming into focus through femtosecond laser spectroscopy. The recently completed map of the human genome and the ever-expanding crystallographic database of nucleic acid structures are two examples that illustrate the richly detailed information currently available about the static properties of nucleic acids. In contrast, much less is known about the dynamics of these macromolecules. This is particularly true of the dynamics of the excited states that play a critical role in DNA photodamage. Efforts to study nucleic acids by time-resolved spectroscopy have been stymied by the apparent lack of suitable fluorophores. In contrast, dynamical spectroscopy of proteins has flourished thanks to intrinsically fluorescent amino acids such as tryptophan, tyrosine, and phenylalanine.4 The primary UVabsorbing constituents of nucleic acids, the nucleic acid bases, have vanishingly small fluorescence quantum yields under physiological conditions of temperature and pH.5 In fact, the bases were frequently described as “nonfluorescent” in the early literature. * To whom correspondence should be addressed. E-mail: kohler@ chemistry.ohio-state.edu. Phone: (614) 688-3944. Fax: (614) 2921685. 1977 Chem. Rev. 2004, 104, 1977−2019

Ultrafast Excited-State Dynamics in Nucleic Acids

Consider a discrete source producing a sequence of message letters from a finite alphabet. A single-letter distortion measure is given by a non-negative matrix (d ij ). The entryd ij measures the ?cost? or ?distortion? if letteriis reproduced at the receiver as letterj. The average distortion of a communications system (source-coder-noisy channel-decoder) is taken to bed= ? i.j P ij d ij whereP ij is the probability ofibeing reproduced asj. It is shown that there is a functionR(d) that measures the ?equivalent rate? of the source for a given level of distortion. For coding purposes where a leveldof distortion can be tolerated, the source acts like one with information rateR(d). Methods are given for calculatingR(d), and various properties discussed. Finally, generalizations to ergodic sources, to continuous sources, and to distortion measures involving blocks of letters are developed. In this paper a study is made of the problem of coding a discrete source of information, given afidelity criterionor ameasure of the distortionof the final recovered message at the receiving point relative to the actual transmitted message. In a particular case there might be a certain tolerable level of distortion as determined by this measure. It is desired to so encode the information that the maximum possible signaling rate is obtained without exceeding the tolerable distortion level. This work is an expansion and detailed elaboration of ideas presented earlier [1], with particular reference to the discrete case. We shall show that for a wide class of distortion measures and discrete sources of information there exists a functionR(d) (depending on the particular distortion measure and source) which measures, in a sense, the equivalent rateRof the source (in bits per letter produced) whendis the allowed distortion level. Methods will be given for evaluatingR(d) explicitly in certain simple cases and for evaluatingR(d) by a limiting process in more complex cases. The basic results are roughly that it is impossible to signal at a rate faster thanC/R(d) (source letters per second) over a memoryless channel of capacityC(bits per second) with a distortion measure less than or equal tod. On the other hand, by sufficiently long block codes it is possible to approach as closely as desired the rateC/R(d) with distortion leveld. Finally, some particular examples, using error probability per letter of message and other simple distortion measures, are worked out in detail.

Coding Theorems for a Discrete Source With a Fidelity CriterionInstitute of Radio Engineers, International Convention Record, vol. 7, 1959.

The spatial features of emitted wireless signals are the basis of location distinction and determination for wireless indoor localization. Available in mainstream wireless signal measurements, the Received Signal Strength Indicator (RSSI) has been adopted in vast indoor localization systems. However, it suffers from dramatic performance degradation in complex situations due to multipath fading and temporal dynamics. Break-through techniques resort to finer-grained wireless channel measurement than RSSI. Different from RSSI, the PHY layer power feature, channel response, is able to discriminate multipath characteristics, and thus holds the potential for the convergence of accurate and pervasive indoor localization. Channel State Information (CSI, reflecting channel response in 802.11 a/g/n) has attracted many research efforts and some pioneer works have demonstrated submeter or even centimeter-level accuracy. In this article, we survey this new trend of channel response in localization. The differences between CSI and RSSI are highlighted with respect to network layering, time resolution, frequency resolution, stability, and accessibility. Furthermore, we investigate a large body of recent works and classify them overall into three categories according to how to use CSI. For each category, we emphasize the basic principles and address future directions of research in this new and largely open area.

From RSSI to CSI: Indoor Localization via Channel Response, A survey on indoor localization using PHY-layer information

Cytosine excited state dynamics studied by femtosecond fluorescence upconversion and transient absorption spectroscopy

This paper describes ideas and items of work within the
framework of the EU-funded 4WARD project. We present
scenarios where the current host-centric approach to infor-
mation storage and retrieval is ill-suited for and explain
how a new networking paradigm emerges, by adopting the
information-centric network architecture approach, which
we call Network of Information (NetInf). NetInf capital-
izes on a proposed identifier/locator split and allows users
to create, distribute, and retrieve information using a com-
mon infrastructure without tying data to particular hosts.
NetInf introduces the concepts of information and data ob-
jects. Data objects correspond to the particular bits and
bytes of a digital object, such as text file, a specific encod-
ing of a song or a video. Information objects can be used
to identify other objects irrespective of their particular dig-
ital representation. After discussing the benefits of such an
indirection, we consider the impact of NetInf with respect
to naming and governance in the Future Internet. Finally,
we provide an outlook on the research scope of NetInf along
with items for future work.

/pdf/scenarios-and-research-issues-for-a-network-of-information-13uit12d93.pdf

Scenarios and Research Issues for a Network of Information

Wireless body area network (WBAN) is an emerging research field particularly in the area of remote health monitoring. For the simple reason that health data are private and sensitive information, securing access and data transmission within a WBAN becomes a critical need. Using certificates requires deploying Public Key Infrastructure (PKI) and Certification Authorities (CA) and their management (control the generation, transmission and revocation) is a cumbersome task unlike identity-based cryptography concept. Considering the heterogeneity between participating tiers in the network, we propose in this paper a hybrid authentication and key agreement scheme where symmetric cryptography is used in sensor/actuator nodes while identity-based cryptography concept is used between smartphone (MN) and the storage site (SS). We present two protocols to authenticate and establish pairwise and group keys between all tiers and to provide a public and private keys for MNs.

A Hybrid Authentication and Key Establishment Scheme for WBAN

This article proposes two new mechanisms to allow a fair power consumption in mobile ad-hoc networks using the OLSR routing protocol. The key element of OLSR is the election of special nodes called MPR nodes which are designed to broadcast control packets. We propose to introduce new MPR selection criteria which take into account the energy capacity of nodes. This paper presents some simulation results which highlight the performance of our proposition in comparison to the classical OLSR.

New energy saving mechanisms for mobile ad-hoc networks using OLSR

Indoor Localization has attracted interest in both academia and industry for its wide range of applications. In this paper, we propose an indoor localization solution based on Channel State Information (CSI). CSI is a fine-grain measure of the effect of the channel on the transmitted signal. It is computed for each subcarrier and each antenna in the Multiple-Input-Multiple-Output (MIMO) antenna case. It is also becoming a trend for indoor position fingerprinting. By using a K-nearest neighbor learning method a highly accurate indoor positioning is achieved. The input feature is the magnitude component of CSI which is preprocessed to reduce noise and allow for a quicker search. The euclidean distance between CSI is the criteria chosen for measuring the closeness between samples. The method is applied to a CSI dataset estimated at an $8\times 2$ MIMO antenna that is published by the organizers of the Communication Theory Workshop Indoor Positioning Competition. The proposed method is compared with three other methods all based on deep learning approaches and tested with the same dataset. The Knearest neighbor method presented in this paper achieves a Mean Square Error (MSE) of 2.4 cm which outperforms its counterparts.

/pdf/csi-mimo-k-nearest-neighbor-applied-to-indoor-localization-37cyuefks2.pdf

Eric Renault

Papers

Cytosine excited state dynamics studied by femtosecond fluorescence upconversion and transient absorption spectroscopy

Scenarios and Research Issues for a Network of Information

A Hybrid Authentication and Key Establishment Scheme for WBAN

New energy saving mechanisms for mobile ad-hoc networks using OLSR

CSI-MIMO: K-nearest Neighbor applied to Indoor Localization.