F
F. Albert Cotton
Researcher at Florida State University
Publications - 15
Citations - 793
F. Albert Cotton is an academic researcher from Florida State University. The author has contributed to research in topics: Extended metal atom chains & Magnetic susceptibility. The author has an hindex of 14, co-authored 15 publications receiving 769 citations. Previous affiliations of F. Albert Cotton include Sun Yat-sen University & University of Miami.
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Molecular and Electronic Structures by Design: Tuning Symmetrical and Unsymmetrical Linear Trichromium Chains
TL;DR: The preparation, properties, and crystal structures of 12 trichromium extended metal atom chain (EMAC) compounds of the type Cr(3)(L)(4)X(2) with large variations in metal-metal distances are reported here and important comparisons with a reported DFT model of the electronic structures of the compounds are made.
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Additional Steps toward Molecular Scale Wires: Further Study of Ni510/11+ Chains Embraced by Polypyridylamide Ligands
TL;DR: This paper presents two advances in the development of the chemistry of extended metal atom chains (EMACs) that employ di(2-pyridyl)amide (dpa) and its higher homologues (loosely called polypyridylamides) as EMACs employing these ligands are extended to greater lengths, low solubility becomes an increasingly difficult problem.
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Observation of Symmetry Lowering and Electron Localization in the Doublet-States of a Spin-Frustrated Equilateral Triangular Lattice: Cu3(O2C16H23)·1.2C6H12
TL;DR: The detailed magnetic measurements on a three-electron, equilateral triangular system, and the observation of symmetry lowering in the doublet ground state, should be of broad theoretical and experimental interest in molecular magnetism.
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Modeling spin interactions in a cyclic trimer and a cuboidal Co4O4 core with Co(II) in tetrahedral and octahedral environments.
John F. Berry,F. Albert Cotton,Chun Y. Liu,Tongbu Lu,Carlos A. Murillo,Boris Tsukerblat,Dino Villagrán,Xiaoping Wang +7 more
TL;DR: The X-ray crystallographic structures, the magnetic susceptibilities from 2 to 300 K, and a theoretical analysis of the magnetism for a triangular and a tetranuclear molecule consisting of linked high-spin cobalt(II) centers are described.
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Enhancing the stability of trinickel molecular wires and switches: Ni36+/Ni37+
TL;DR: In this article, the authors describe four new compounds that contain extended metal atom chains (EMACs) of three nickel atoms wrapped by either di(2-pyridyl)amide (dpa) or the new homologous ligand with an ethyl group at the para position of each pyridine group, depa.