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F

F. Buchter

Researcher at Swiss Federal Laboratories for Materials Science and Technology

Publications -  20
Citations -  1264

F. Buchter is an academic researcher from Swiss Federal Laboratories for Materials Science and Technology. The author has contributed to research in topics: Hydrogen & Hydrogen storage. The author has an hindex of 15, co-authored 20 publications receiving 1175 citations. Previous affiliations of F. Buchter include University of Fribourg & Paul Scherrer Institute.

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Journal ArticleDOI

Stability and reversibility of LiBH4.

TL;DR: The stability of LiBH4 was investigated by pcT (pressure, concentration, and temperature) measurements under constant hydrogen flows and extrapolated to equilibrium by XRD (X-ray diffraction), and it was shown that the reaction can be reversed at a temperature of 600 degrees C and at a pressure of 155 bar.
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In situ synchrotron diffraction studies of phase transitions and thermal decomposition of Mg(BH4)2 and Ca(BH4)2

TL;DR: In this article, the properties of Mg(BH4)2 and Ca(bH42)2 with 14.9 and 11.6 mass% hydrogen were studied by time-resolved in situ synchrotron powder X-ray diffraction, thermal desorption spectroscopy and energy dispersive Xray spectrographs.
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Hydrogen storage properties of Mg[BH4]2

TL;DR: In this article, the authors investigated the reaction of Li[BH 4 ] with MgCl 2 at elevated temperatures and found that only the second reaction step (MgH 2 ǫ→ Mg) is reversible at the condition up to 623 K at 10 MPa of hydrogen.
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Structure of Ca(BD4)2 β-Phase from Combined Neutron and Synchrotron X-ray Powder Diffraction Data and Density Functional Calculations

TL;DR: Combined experimental and ab initio calculations have shown that the best description of the structure is with the space group P4(2)/m based on appropriate size/geometry of the (BD4)tetrahedra, the lowest calculated formation energy, and real positive vibrational energy, indicating a stable structure.
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Magnesium borohydride: A new hydrogen storage material

TL;DR: In this paper, a two-stage reaction was shown for the decomposition of LiBH 4 with MgCl 2 by heat treatment without using a solvent, where the product consists of LiCl and a compound of magnesium, boron and hydrogen.