This paper describes a solution-based, precursor method for the facile synthesis of uniform nanowires containing rutile SnO2 nanocrystallites. In a typical procedure, nanowires of ∼50 nm in diamete...

A solution-phase, precursor route to polycrystalline SnO2 nanowires that can be used for gas sensing under ambient conditions.

A magnetotransport study of zirconium pentatelluride now reveals evidence for a chiral magnetic effect, a striking macroscopic manifestation of the quantum and relativistic nature of Weyl semimetals The chiral magnetic effect is the generation of an electric current induced by chirality imbalance in the presence of a magnetic field It is a macroscopic manifestation of the quantum anomaly1,2 in relativistic field theory of chiral fermions (massless spin 1/2 particles with a definite projection of spin on momentum)—a remarkable phenomenon arising from a collective motion of particles and antiparticles in the Dirac sea The recent discovery3,4,5,6 of Dirac semimetals with chiral quasiparticles opens a fascinating possibility to study this phenomenon in condensed matter experiments Here we report on the measurement of magnetotransport in zirconium pentatelluride, ZrTe5, that provides strong evidence for the chiral magnetic effect Our angle-resolved photoemission spectroscopy experiments show that this material’s electronic structure is consistent with a three-dimensional Dirac semimetal We observe a large negative magnetoresistance when the magnetic field is parallel with the current The measured quadratic field dependence of the magnetoconductance is a clear indication of the chiral magnetic effect The observed phenomenon stems from the effective transmutation of a Dirac semimetal into a Weyl semimetal induced by parallel electric and magnetic fields that represent a topologically non-trivial gauge field background We expect that the chiral magnetic effect may emerge in a wide class of materials that are near the transition between the trivial and topological insulators

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Chiral magnetic effect in ZrTe 5

The sharp structure observed in the fundamental optical spectra of crystals, both vibrational and electronic, can be classified and interpreted by symmetry arguments based explicitly on the existence of long-range order. Indeed, this is one of the few properties of crystals which cannot be accounted for on the basis of short-range order alone: If the long-range order is destroyed, the sharp structural detail, which is typical for crystals, disappears. However, the broad features of the spectra are similar if the short-range order is similar.

Optical Properties of Amorphous Semiconductors

Intercalation and exfoliation of lithium: Few-layer-thick inorganic nanosheets (BN, NbSe(2), WSe(2), Sb(2)Se(3), and Bi(2)Te(3)) have been prepared from their layered bulk precursors by using a controllable electrochemical lithium intercalation process. The lithium intercalation conditions, such as cut-off voltage and discharge current, have been systematically studied and optimized to produce high-quality BN and NbSe(2) nanosheets.

An Effective Method for the Fabrication of Few‐Layer‐Thick Inorganic Nanosheets

A simple and convenient method has been demonstrated for large-scale synthesis of metal oxide (including TiO2, SnO2, In2O3, and PbO) nanowires with diameters around 50 nm and lengths up to 30 µm. In a typical procedure, tetraalkoxyltitanium, Ti(OR)4
				(with R =
				–C2H5, –iso-C3H7, or –n-C4H9), was added to ethylene glycol and heated to 170 °C for 2 h under vigorous stirring. The alkoxide was transformed into a chain-like, glycolate complex that subsequently crystallized into uniform nanowires. Similarly, nanowires made of tin glycolate were synthesized by refluxing SnC2O4·2H2O in ethylene glycol at 195 °C for 2 h, and nanowires consisting of indium and lead glycolates were prepared by adding In(OOCC7H15)(OiPr)2 and Pb(CH3COO)2 to ethylene glycol, followed by heating at 170 °C for 2 h. The nanowires could be readily collected as precipitates after the reaction solutions had been cooled down to room temperature. By calcining at elevated temperatures, each glycolate precursor could be transformed into the corresponding metal oxide without changing the wire-like morphology. Electron microscopic and XRD powder diffraction studies were used to characterize the morphology, crystallinity, and structure of these nanowires before and after calcination at various temperatures. A plausible mechanism was also proposed to account for the one-dimensional growth of such nanostructures in a highly isotropic medium. This mechanism was supported by XRD, FT-IR, solid state 13C-NMR, and TGA measurements. As a demonstration of potential applications, the polycrystalline nanowires made of SnO2 were used as functional components to fabricate sensors that could detect combustible gases (CO and H2) with greatly enhanced sensitivity under ambient conditions.

F.J. DiSalvo

Papers

Valence bands of layer structure transition metal chalcogenides

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Stoichiometry and physical properties of ternary molybdenum chalcogenides MxMo6X8 (X = S, Se; M = Li, Sn, Pb)