F
Frank van Mourik
Researcher at École Polytechnique Fédérale de Lausanne
Publications - 65
Citations - 3089
Frank van Mourik is an academic researcher from École Polytechnique Fédérale de Lausanne. The author has contributed to research in topics: Excited state & Spectroscopy. The author has an hindex of 27, co-authored 60 publications receiving 2893 citations. Previous affiliations of Frank van Mourik include Academy of Sciences of the Czech Republic & VU University Amsterdam.
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Journal ArticleDOI
Ultrafast Nonadiabatic Dynamics of [FeII(bpy)3]2+ in Solution
Wojciech Gawelda,Andrea Cannizzo,Van-Thai Pham,Frank van Mourik,Christian Bressler,Majed Chergui +5 more
TL;DR: A simple model of avoided crossings between singlet and triplet potential curves, induced by the strong spin-orbit interaction is proposed, which concludes that the ultrafast relaxation of aqueous iron(II)-tris(bipyridine) upon excitation into the singlet metal-to-ligand charge-transfer band can be described by the Fermi golden rule, despite its high value.
Journal ArticleDOI
Excitation Transfer in the Core Light-Harvesting Complex (LH-1) of Rhodobacter sphaeroides: An Ultrafast Fluorescence Depolarization and Annihilation Study
TL;DR: Oscillations in the isotropic fluorescence with a 105 cm-' frequency suggest wave-packet motion in the excited state chromophore in analogy with the reaction center special pair, which is supporting evidence for the hypothesis that the LH-1 antenna is built of bacteriochlorophyll dimers.
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Broadband femtosecond fluorescence spectroscopy of [Ru(bpy)3]2+
Andrea Cannizzo,Frank van Mourik,Wojciech Gawelda,Goran Zgrablić,Christian Bressler,Majed Chergui +5 more
TL;DR: Femtosecond fluorescence-upconversion studies of aq.2+ show a short-lived vibrationally hot emission of the singlet metal-to-ligand charge-transfer state, with an ultrafast intersystem crossing to the triplet state at const.
Journal ArticleDOI
Vibrational Coherences and Relaxation in the High-Spin State of Aqueous [FeII(bpy)3]2+
Cristina Consani,Mirabelle Prémont-Schwarz,Amal Elnahhas,Christian Bressler,Frank van Mourik,Andrea Cannizzo,Majed Chergui +6 more
TL;DR: The vibrational relaxation involves at least two modes: the FeN stretching mode and the coherently excited chelate-ring and bending mode, which relax on different time scales.
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Ultrafast tryptophan-to-heme electron transfer in myoglobins revealed by UV 2D spectroscopy.
TL;DR: Using ultra-broadband ultrafast two-dimensional spectroscopy in the ultraviolet (UV) and transient absorption in the visible range, the excited state decay pathways of the tryptophan amino acid residues in ferric myoglobins are disentangled.