Cometary nuclei contain the least modified material from the formative epoch of our planetary system, and their compositions reflect a range of processes experienced by material prior to its incorporation in the cometary nucleus. Dynamical models suggest that icy bodies in the main cometary reservoirs (Kuiper Belt, Oort Cloud) formed in a range of environments in the protoplanetary disk, and (for the Oort Cloud) even in disks surrounding neighboring stars of the Sun's birth cluster. Photometric and spectroscopic surveys of more than 100 comets have enabled taxonomic groupings based on free radical species and on crystallinity of rocky grains. Since 1985, new surveys have provided emerging taxonomies based on the abundance ratios of primary volatiles. More than 20 primary chemical species are now detected in bright comets. Measurements of nuclear spin ratios (in water, ammonia, and methane) and of isotopic ratios (D/H in water and HCN; 14N/15N in CN and HCN) have provided critical insights on factors affec...

The Chemical Composition of Comets—Emerging Taxonomies and Natal Heritage

Following the encounter of the Vega 1 spacecraft with comet Halley, the composition of cometary dust has been analysed by mass spectroscopy. Most particles consist of a predominantly chondritic core with an organic mantle composed mainly of highly unsaturated compounds.

The organic component in dust from comet Halley as measured by the PUMA mass spectrometer on board Vega 1

Understanding how comets work, i,e., what drives their activity, is crucial to using comets to study the early solar system. EPOXI flew past comet 103P/Hartley 2, one with an unusually small but very active nucleus. taking both images and spectra. Unlike large, relatively inactive nuclei, this nncleus is outgassing primarily due to CO2, which drags chnnks of ice out of the nnclens. It also shows significant differences in the relative abundance of volatiles from various parts of the nucleus.

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EPOXI at Comet Hartley 2

The chemical composition of the solid grains from comet Halley can be inferred from impact-ionization time-of-flight mass spectrometry Halley's dust in the vicinity of the VEGA-1 spacecraft is a mixture of a refractory organic component and unequilibrated silicates, but detailed chemical information on individual particles is difficult to extract because of the complexity of the impact-ionization process

Aspects of the major element composition of Halley's dust

The Giotto space probe's ion mass spectrometer has obtained data on the composition and velocity distributions of cometary ions at distances of between 7.5 million and 1300 km from the comet Halley nucleus. Solar wind He(2+) was found throughout the coma, as close as 5000 km, with the He(+) produced by charge exchange being within about 200,000 km. A pile-up of heavy cometary ions was found at about 10,000 km from the nucleus. Inside the contact surface, which was found at about 4600 km, ion temperatures as low as about 340 K and outflow velocities of about 1 km/sec were found.

Ion composition and dynamics at comet Halley

Mass spectra of cometary dust particles measured by the PIA dust particle analyzer aboard the Giotto spacecraft show some unexpected and striking features. First, small particles below 10 to the -14th g are much more abundant than anticipated by models. Second, most of the particles are rich in light elements such as H, C, N, and O, suggesting the validity of models that describe the cometary dust as including organic material. Third, the light elements specifically seem to have a low ratio of mass to volume. Three examples of original mass spectra showing typical compositions are given; these have been measured, and are compared with a computer-simulated mass spectrum.

G. M. Morfill

Papers

Composition of comet Halley dust particles from Giotto observations