G
Garret M. Miyake
Researcher at Colorado State University
Publications - 104
Citations - 6092
Garret M. Miyake is an academic researcher from Colorado State University. The author has contributed to research in topics: Polymerization & Atom-transfer radical-polymerization. The author has an hindex of 37, co-authored 98 publications receiving 4630 citations. Previous affiliations of Garret M. Miyake include Nagoya University & University of Colorado Boulder.
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Journal ArticleDOI
Organocatalyzed atom transfer radical polymerization driven by visible light
Jordan C. Theriot,Chern-Hooi Lim,Haishen Yang,Matthew D. Ryan,Charles B. Musgrave,Garret M. Miyake +5 more
TL;DR: Diaryl dihydrophenazines are introduced, identified through computationally directed discovery, as a class of strongly reducing photoredox catalysts that achieve high initiator efficiencies through activation by visible light to synthesize polymers with tunable molecular weights and low dispersities.
PatentDOI
Rapid self-assembly of block copolymers to photonic crystals
Yan Xia,Benjamin R. Sveinbjornsson,Robert H. Grubbs,Raymond Weitekamp,Garret M. Miyake,Harry A. Atwater,Victoria A. Piunova,Christopher Daeffler,Sung Woo Hong,Weiyin Gu,Russell Thomas +10 more
TL;DR: The block copolymers of as discussed by the authors incorporate chemically different blocks comprising polymer size chain groups and/or wedge groups that significantly inhibit chain entanglement, thereby enhancing molecular self-assembly processes for generating a range of supramolecular structures.
Journal ArticleDOI
Visible-Light-Promoted C–S Cross-Coupling via Intermolecular Charge Transfer
TL;DR: UV-vis spectroscopy and time-dependent density functional theory calculations suggest that visible-light-promoted intermolecular charge transfer within the thiolate-aryl halide electron donor-acceptor complex permits the reactivity in the absence of catalyst.
Journal ArticleDOI
Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
TL;DR: In this article, the generation of carbon-centered radicals from alkyl bromides through an oxidative quenching pathway using perylene as an organic visible-light photocatalyst is described.
Journal ArticleDOI
Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts
TL;DR: A key finding reveals that maintenance of a planar conformation of the phenoxazine catalyst during the catalytic cycle encourages the synthesis of well-defined macromolecules.