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Georgios C. Vougioukalakis

Researcher at National and Kapodistrian University of Athens

Publications -  89
Citations -  3704

Georgios C. Vougioukalakis is an academic researcher from National and Kapodistrian University of Athens. The author has contributed to research in topics: Catalysis & Chemistry. The author has an hindex of 21, co-authored 80 publications receiving 3256 citations. Previous affiliations of Georgios C. Vougioukalakis include California Institute of Technology & Massachusetts Institute of Technology.

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Unprecedented Multicomponent Organocatalytic Synthesis of Propargylic Esters via CO2 Activation

TL;DR: The contribution of COST Action CA15106 (C−H Activation in Organic Synthesis-CHAOS) was acknowledged by the authors of as discussed by the authors, who are also grateful for the technical and human support provided by IZO-SGI SGIker of UPV/EHU, and the European Funding Horizon 2020-MSCA (ITN-EJD CATMEC 14/06-721223)
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Photocatalytic Atom Transfer Radical Addition to Olefins Utilizing Novel Photocatalysts.

TL;DR: The tailor-made ruthenium-based catalyst bearing the pyridine-quinoline bidentate ligand proved to be the best-performing photocatalyst, among a range of metal complexes and organocatalysts, efficiently catalyzing both reactions.
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Synthesis and self-photooxygenation of alkenyl-linked [60]fullerene derivatives. A regioselective ene reaction.

TL;DR: Alkenyl-linked C(60) derivatives undergo self-photooxygenation regioselectively, by the preferential abstraction of allylic hydrogens on the fullerene side of the double bond.
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Green asymmetric synthesis: β-amino alcohol-catalyzed direct asymmetric aldol reactions in aqueous micelles.

TL;DR: A family of cheap and easily accessible β-amino alcohols was shown to successfully catalyze the asymmetric aldol reaction between a series of ketones and aromatic aldehydes, which furnished the corresponding β-hydroxy ketones with up to 93% isolated yield and 89% ee.
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Addition of Electron-Rich Aromatics to Azafullerenium Carbocation. A Stepwise Electrophilic Substitution Mechanism

TL;DR: The measured intermolecular kinetic isotope effects are consistent with an electrophilic aromatic substitution mechanism in which the arenium cation is formed by Electrophilic attack of C(59)N(+) on the aromatic ring in the first step of the reaction, followed by hydrogen abstraction in a rate-determining second step.