G
Gerard Parkin
Researcher at Columbia University
Publications - 362
Citations - 15030
Gerard Parkin is an academic researcher from Columbia University. The author has contributed to research in topics: Ligand & Reactivity (chemistry). The author has an hindex of 62, co-authored 357 publications receiving 14087 citations. Previous affiliations of Gerard Parkin include University of Oxford & California Institute of Technology.
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Agostic interactions in transition metal compounds
TL;DR: The impact of agostic interactions (i.e., 3-center–2-electron MHC bonds) on the structures and reactivity of organotransition metal compounds is reviewed.
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Synthetic analogues relevant to the structure and function of zinc enzymes.
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The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds
TL;DR: This article provides an extension to the Covalent Bond Classification (CBC) method by categorizing 3c-2e interactions according to whether (i) the two electrons are provided by one or by two atoms and (ii) the central bridging atom provides two, one, or zero electrons.
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Zinc catalysts for on-demand hydrogen generation and carbon dioxide functionalization.
Wesley Sattler,Gerard Parkin +1 more
TL;DR: A multifunctional catalyst capable of achieving rapid release of hydrogen by protolytic cleavage of silanes with either water or methanol and hydrosilylation of aldehydes, ketones, and carbon dioxide, thereby providing a means for utilizing carbon dioxide as a C(1) feedstock for the synthesis of useful chemicals.
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A simple description of the bonding in transition-metal borane complexes
TL;DR: The use of oxidation numbers to determine the dn configuration of metal borane compounds (M→BX3) is problematic due to differences in opinion concerned with the charge assigned to the BX3 ligand.