G
Gerhard Hilt
Researcher at University of Marburg
Publications - 247
Citations - 6031
Gerhard Hilt is an academic researcher from University of Marburg. The author has contributed to research in topics: Catalysis & Cobalt. The author has an hindex of 41, co-authored 242 publications receiving 5424 citations. Previous affiliations of Gerhard Hilt include Ludwig Maximilian University of Munich & University of Oldenburg.
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Asymmetric photoredox transition-metal catalysis activated by visible light
Haohua Huo,Xiaodong Shen,Chuanyong Wang,Lilu Zhang,Philipp Röse,Liang-An Chen,Klaus Harms,Michael Marsch,Gerhard Hilt,Eric Meggers +9 more
TL;DR: It is shown that a chiral iridium complex can serve as a sensitizer for photoredox catalysis and at the same time provide very effective asymmetric induction for the enantioselective alkylation of 2-acyl imidazoles.
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trans-RuH(η1-BH4)(binap)(1,2-diamine): A Catalyst for Asymmetric Hydrogenation of Simple Ketones under Base-Free Conditions
TL;DR: The TolBINAP/DPEN Ru complex allows for asymmetric hydrogenation of simple ketones in 2-propanol without an additional strong base and overcomes the drawback of an earlier method using RuCl2(diphosphine)(diamine) and an alkaline base.
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Assembling molecular Sierpiński triangle fractals
Jian Shang,Yongfeng Wang,Min Chen,Jingxin Dai,Xiong Zhou,Julian Kuttner,Gerhard Hilt,Xiang Shao,J. Michael Gottfried,Kai Wu +9 more
TL;DR: The formation of synergistic halogen and hydrogen bonds between these molecules is the driving force to assemble successfully a whole series of defect-free molecular fractals, specifically Sierpiński triangles, on a Ag(111) surface below 80 K.
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Surface‐Assisted Organic Synthesis of Hyperbenzene Nanotroughs
Qitang Fan,Cici Wang,Yong Han,Junfa Zhu,Wolfgang Hieringer,Julian Kuttner,Gerhard Hilt,J. Michael Gottfried +7 more
TL;DR: A hexagonal macrocycle consisting of 18 phenylene units (hyperbenzene) was synthesized on a Cu(111) surface in ultrahigh vacuum by Ullmann coupling of six 4,4''-dibromo-m-terphenyl molecules to create a hexagonal nanotrough that could enclose metallic, semiconducting, or molecular quantum dots.
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A self-assembled metallomacrocyclic ionophore with high affinity and selectivity for Li+ and Na+.
TL;DR: Preliminary results indicate that structurally related metallacrown ethers having different arene ligands instead of cymene can be assembled using the strategy described here, and redox-responsive receptors with designed specificities and solubilities can be envisioned.