The development of novel materials is a fundamental focal point of chemical research; and this interest is mandated by advancements in all areas of industry and technology. A good example of the synergism between scientific discovery and technological development is the electronics industry, where discoveries of new semiconducting materials resulted in the evolution from vacuum tubes to diodes and transistors, and eventually to miniature chips. The progression of this technology led to the development * To whom correspondence should be addressed. B.L.C.: (504) 2801385 (phone); (504) 280-3185 (fax); bcushing@uno.edu (e-mail). C.J.O.: (504)280-6846(phone);(504)280-3185(fax);coconnor@uno.edu (e-mail). 3893 Chem. Rev. 2004, 104, 3893−3946

http://depa.fquim.unam.mx/amyd//archivero/FidelmarLechugaSanabria_4940.pdf

Recent advances in the liquid-phase syntheses of inorganic nanoparticles.

UV-Visible ار راد ن .د TiO2 ( تیفرظ راون مان هب نورتکلا یاراد یژرنا زارت لماش VB و ) رگید زارت ی یژرنا اب ( ییاناسر راون مان هب نورتکلا زا یلاخ و رتلااب VB یم ) .دشاب ت ود نیا نیب یژرنا توافت یژرنا فاکش زار ، پگ دناب هدیمان یم .دوش هک ینامز زا نورتکلا لاقتنا VB هب VB یم ماجنا دریگ ، TiO2 اب ودح یژرنا بذج د ev 2 / 3 ، نورتکلا تفج کی دیلوت یم هرفح .دیامن و نورتکلا هرفح ی نا اب هدش دیلوت یم کرتشم حطس هب لاقت ثعاب دناوت شنکاو ماجنا اه یی ددرگ . TiO2 دربراک ،دراد یدایز یاه هلمج زا یم ناوت اوه یگدولآ هیفصت یارب (CO2) و بآ و ... نآ زا هدافتسا درک .

Advanced Nanoarchitectures for Solar Photocatalytic Applications

This article provides an up-to-date perspective on the use of anion-exchange membranes in fuel cells, electrolysers, redox flow batteries, reverse electrodialysis cells, and bioelectrochemical systems (e.g. microbial fuel cells). The aim is to highlight key concepts, misconceptions, the current state-of-the-art, technological and scientific limitations, and the future challenges (research priorities) related to the use of anion-exchange membranes in these energy technologies. All the references that the authors deemed relevant, and were available on the web by the manuscript submission date (30th April 2014), are included.

/pdf/anion-exchange-membranes-in-electrochemical-energy-systems-46uquenb56.pdf

Anion-exchange membranes in electrochemical energy systems

Recent research results pertaining to InN, GaN and AlN are reviewed, focusing on the different growth techniques of Group III-nitride crystals and epitaxial films, heterostructures and devices. The chemical and thermal stability of epitaxial nitride films is discussed in relation to the problems of deposition processes and the advantages for applications in high-power and high-temperature devices. The development of growth methods like metalorganic chemical vapour deposition and plasma-induced molecular beam epitaxy has resulted in remarkable improvements in the structural, optical and electrical properties. New developments in precursor chemistry, plasma-based nitrogen sources, substrates, the growth of nucleation layers and selective growth are covered. Deposition conditions and methods used to grow alloys for optical bandgap and lattice engineering are introduced. The review is concluded with a description of recent Group III-nitride semiconductor devices such as bright blue and white light-emitting diodes, the first blue-emitting laser, high-power transistors, and a discussion of further applications in surface acoustic wave devices and sensors.

https://iopscience.iop.org/article/10.1088/0022-3727/31/20/001/pdf

Growth and applications of Group III-nitrides

This review highlights recent developments and future perspectives in carbon dioxide usage for the sustainable production of energy and chemicals and to reduce global warming. We discuss the heterogeneously catalysed hydrogenation, as well as the photocatalytic and electrocatalytic conversion of CO2 to hydrocarbons or oxygenates. Various sources of hydrogen are also reviewed in terms of their CO2 neutrality. Technologies have been developed for large-scale CO2 hydrogenation to methanol or methane. Their industrial application is, however, limited by the high price of renewable hydrogen and the availability of large-volume sources of pure CO2. With regard to the direct electrocatalytic reduction of CO2 to value-added chemicals, substantial advances in electrodes, electrolyte, and reactor design are still required to permit the development of commercial processes. Therefore, in this review particular attention is paid to (i) the design of metal electrodes to improve their performance and (ii) recent developments of alternative approaches such as the application of ionic liquids as electrolytes and of microorganisms as co-catalysts. The most significant improvements both in catalyst and reactor design are needed for the photocatalytic functionalisation of CO2 to become a viable technology that can help in the usage of CO2 as a feedstock for the production of energy and chemicals. Apart from technological aspects and catalytic performance, we also discuss fundamental strategies for the rational design of materials for effective transformations of CO2 to value-added chemicals with the help of H2, electricity and/or light.

/pdf/status-and-perspectives-of-co2-conversion-into-fuels-and-aitrajygas.pdf

Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes

Effect of Gd (Sm) doping on properties of ceria electrolyte for solid oxide fuel cells

Separation of stable oil–water emulsion by the hydrophilic nano-sized ZrO2 modified Al2O3 microfiltration membrane

A high-performance ammonia-fueled solid oxide fuel cell

This article provides a brief review of the cathode reaction mechanisms in proton-conducting solid oxide fuel cells (H-SOFCs) and a comparative analysis of electrochemical performance and the ionic and electronic transport in cathode materials. The transfer of protons from electrolyte to triple phase boundaries (TPBs) and the diffusion of O−ad from catalytic sites to TPBs are proposed to be the rate-limiting steps for H-SOFCs, of which the latter is more related to the cathode components, microstructure, conducting species and electrical conductivity. The experimental and theoretical analyses also suggest that cathode materials with electron and proton conductivity present smaller polarisation resistances due to the ability of protons to transfer from the electrolyte into the bulk, which extends the reaction areas for protons and oxygen species to the entire gas/cathode surface.

Cathode processes and materials for solid oxide fuel cells with proton conductors as electrolytes

Synthetic fuels produced from CO2/H2O are an attractive alternative energy carrier. Here we demonstrate a novel strategy to electrochemically convert CO2/H2O into hydrocarbon in a single step in an oxygen-ion conducting solid oxide electrolyser. Methane was directly synthesized in an efficient electrolyser with configuration of (anode) (La0.8Sr0.2)0.95MnO3−δ/YSZ/La0.2Sr0.8TiO3+δ (cathode) by combining coelectrolysis of CO2/H2O and in situ Fischer–Tropsch-type synthesis. We demonstrate a high Faradaic yield of CO/H2 and lower methane yield, which shows that the limit on conversion efficiency comes from the heterogeneous catalysis process. Electrochemical results also show that the electrochemical reduction of La0.2Sr0.8TiO3+δ cathode is the main process at low electrical voltages while the coelectrolysis is the main process at high voltages.

Guangyao Meng

Papers

Effect of Gd (Sm) doping on properties of ceria electrolyte for solid oxide fuel cells

Separation of stable oil–water emulsion by the hydrophilic nano-sized ZrO2 modified Al2O3 microfiltration membrane

A high-performance ammonia-fueled solid oxide fuel cell

Cathode processes and materials for solid oxide fuel cells with proton conductors as electrolytes

Direct synthesis of methane from CO2/H2O in an oxygen-ion conducting solid oxide electrolyser