Recent years have witnessed many breakthroughs in research on graphene (the first two-dimensional atomic crystal) as well as a significant advance in the mass production of this material. This one-atom-thick fabric of carbon uniquely combines extreme mechanical strength, exceptionally high electronic and thermal conductivities, impermeability to gases, as well as many other supreme properties, all of which make it highly attractive for numerous applications. Here we review recent progress in graphene research and in the development of production methods, and critically analyse the feasibility of various graphene applications.

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A roadmap for graphene

The richness of optical and electronic properties of graphene attracts enormous interest. Graphene has high mobility and optical transparency, in addition to flexibility, robustness and environmental stability. So far, the main focus has been on fundamental physics and electronic devices. However, we believe its true potential lies in photonics and optoelectronics, where the combination of its unique optical and electronic properties can be fully exploited, even in the absence of a bandgap, and the linear dispersion of the Dirac electrons enables ultrawideband tunability. The rise of graphene in photonics and optoelectronics is shown by several recent results, ranging from solar cells and light-emitting devices to touch screens, photodetectors and ultrafast lasers. Here we review the state-of-the-art in this emerging field.

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Graphene photonics and optoelectronics

We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field.

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Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems

Graphene has been hailed as a wonderful material in electronics, and recently, it is the rising star in photonics, as well. The wonderful optical properties of graphene afford multiple functions of signal emitting, transmitting, modulating, and detection to be realized in one material. In this paper, the latest progress in graphene photonics, plasmonics, and broadband optoelectronic devices is reviewed. Particular emphasis is placed on the ability to integrate graphene photonics onto the silicon platform to afford broadband operation in light routing and amplification, which involves components like polarizer, modulator, and photodetector. Other functions like saturable absorber and optical limiter are also reviewed.

Graphene photonics, plasmonics, and broadband optoelectronic devices.

Thirty years ago, Coullet et al. proposed that a special optical field exists in laser cavities bearing some analogy with the superfluid vortex. Since then, optical vortices have been widely studied, inspired by the hydrodynamics sharing similar mathematics. Akin to a fluid vortex with a central flow singularity, an optical vortex beam has a phase singularity with a certain topological charge, giving rise to a hollow intensity distribution. Such a beam with helical phase fronts and orbital angular momentum reveals a subtle connection between macroscopic physical optics and microscopic quantum optics. These amazing properties provide a new understanding of a wide range of optical and physical phenomena, including twisting photons, spin-orbital interactions, Bose-Einstein condensates, etc., while the associated technologies for manipulating optical vortices have become increasingly tunable and flexible. Hitherto, owing to these salient properties and optical manipulation technologies, tunable vortex beams have engendered tremendous advanced applications such as optical tweezers, high-order quantum entanglement, and nonlinear optics. This article reviews the recent progress in tunable vortex technologies along with their advanced applications.

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Optical vortices 30 years on: OAM manipulation from topological charge to multiple singularities

Black phosphorus, a newly emerged two-dimensional material, has attracted wide attention as novel photonic material. Here, multilayer black phosphorus is successfully fabricated by liquid phase exfoliation method. By employing black phosphorus as saturable absorber, we demonstrate a passively Q-switched Er-doped ZBLAN fiber laser at the wavelength of 2.8 μm. The modulation depth and saturation fluence of the black phosphorus saturable absorber are measured to be 15% and 9 μJ/cm(2), respectively. The Q-switched fiber laser delivers a maximum average power of 485 mW with corresponding pulse energy of 7.7 μJ and pulse width of 1.18 μs at repetition rate of 63 kHz. To the best of our knowledge, this is the first time to demonstrate that black phosphorus can realize Q-switching of 2.8-μm fiber laser. Our research results show that black phosphorus is a promising saturable absorber for mid-infrared pulsed lasers.

Black phosphorus as saturable absorber for the Q-switched Er:ZBLAN fiber laser at 2.8 μm.

The mode-locking of a ceramic Nd:yttrium aluminum garnet (YAG) solid-state laser (SSL) with solution processed graphene as saturable absorber (SA) was demonstrated. Transform-limited pulses with duration of 4 ps centered at 1064 nm were generated for a nondispersion compensated Nd:YAG SSL. Z-scan studies revealed that the graphene SA has a saturation intensity of 0.87 M W cm−2 and a normalized modulation depth of 17.4%. Our results illustrate the potential of using graphene as a mode locker for SSLs.

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Mode locking of ceramic Nd:yttrium aluminum garnet with graphene as a saturable absorber

Black phosphorus, a newly emerged two-dimensional material, has attracted wide attention as novel photonic material. Here, multi-layer black phosphorus is successfully fabricated by liquid phase exfoliation method. By employing black phosphorus as saturable absorber, we demonstrate a passively Q-switched Er-doped ZBLAN fiber laser at the wavelength of 2.8 {\mu}m. The modulation depth and saturation fluence of the black phosphorus saturable absorber are measured to be 15% and 9 {\mu}J/cm2, respectively. The Q-switched fiber laser delivers a maximum average power of 485 mW with corresponding pulse energy of 7.7 {\mu}J and pulse width of 1.18 {\mu}s at repetition rate of 63 kHz. To the best of our knowledge, this is the first time to demonstrate that black phosphorus can realize Q-switching of 2.8-{\mu}m fiber laser. Our research results show that black phosphorus is a promising saturable absorber for mid-infrared pulsed lasers.

Black phosphorus as saturable absorber for the Q-switched Er:ZBLAN fiber laser at 2.8 {\mu}m

A mid-infrared saturable absorber mirror is successfully fabricated by transferring the mechanically exfoliated black phosphorus onto the gold-coated mirror. With the as-prepared black phosphorus saturable absorber mirror, a continuous-wave passively mode-locked Er:ZBLAN fiber laser is demonstrated at the wavelength of 2.8 μm, which delivers a maximum average output power of 613 mW, a repetition rate of 24 MHz, and a pulse duration of 42 ps. To the best of our knowledge, this is the first time a black phosphorus mode-locked laser at 2.8 μm wavelength has been demonstrated. Our results demonstrate the feasibility of black phosphorus flake as a new two-dimensional material for application in mid-infrared ultrafast photonics.

Mid-infrared mode-locked pulse generation with multilayer black phosphorus as saturable absorber.

We experimentally demonstrated a passively mode-locked femtosecond laser by using a graphene-based saturable absorber mirror (graphene SAM) in the spectral region of 2 μm. The graphene SAM was fabricated by transferring chemical-vapor-deposited, high-quality, and large-area graphene on a highly reflective plane mirror. Stable mode-locked laser pulses as short as 729 fs were obtained with a repetition rate of 98.7 MHz and an average output power of 60.2 mW at 2018 nm.

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Guoqiang Xie

Papers

Black phosphorus as saturable absorber for the Q-switched Er:ZBLAN fiber laser at 2.8 μm.

Mode locking of ceramic Nd:yttrium aluminum garnet with graphene as a saturable absorber

Black phosphorus as saturable absorber for the Q-switched Er:ZBLAN fiber laser at 2.8 {\mu}m

Mid-infrared mode-locked pulse generation with multilayer black phosphorus as saturable absorber.

Graphene mode-locked femtosecond laser at 2 μm wavelength