Statistics for Spatial Data.

DOI 10.1007/s10040-0010176-2 Abstract Various techniques are available to quantify recharge; however, choosing appropriate techniques is often difficult. Important considerations in choosing a technique include space/time scales, range, and reliabili- ty of recharge estimates based on different techniques; other factors may limit the application of particular tech- niques. The goal of the recharge study is important be- cause it may dictate the required space/time scales of the recharge estimates. Typical study goals include water-re- source evaluation, which requires information on re- charge over large spatial scales and on decadal time scales; and evaluation of aquifer vulnerability to contam- ination, which requires detailed information on spatial variability and preferential flow. The range of recharge rates that can be estimated using different approaches should be matched to expected recharge rates at a site. The reliability of recharge estimates using different tech- niques is variable. Techniques based on surface-water and unsaturated-zone data provide estimates of potential recharge, whereas those based on groundwater data gen- erally provide estimates of actual recharge. Uncertainties in each approach to estimating recharge underscore the need for application of multiple techniques to increase

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Choosing appropriate techniques for quantifying groundwater recharge

It is now well understood that data on soil moisture and sea surface salinity (SSS) are required to improve meteorological and climate predictions. These two quantities are not yet available globally or with adequate temporal or spatial sampling. It is recognized that a spaceborne L-band radiometer with a suitable antenna is the most promising way of fulfilling this gap. With these scientific objectives and technical solution at the heart of a proposed mission concept the European Space Agency (ESA) selected the Soil Moisture and Ocean Salinity (SMOS) mission as its second Earth Explorer Opportunity Mission. The development of the SMOS mission was led by ESA in collaboration with the Centre National d'Etudes Spatiales (CNES) in France and the Centro para el Desarrollo Tecnologico Industrial (CDTI) in Spain. SMOS carries a single payload, an L-Band 2-D interferometric radiometer operating in the 1400-1427-MHz protected band . The instrument receives the radiation emitted from Earth's surface, which can then be related to the moisture content in the first few centimeters of soil over land, and to salinity in the surface waters of the oceans. SMOS will achieve an unprecedented maximum spatial resolution of 50 km at L-band over land (43 km on average over the field of view), providing multiangular dual polarized (or fully polarized) brightness temperatures over the globe. SMOS has a revisit time of less than 3 days so as to retrieve soil moisture and ocean salinity data, meeting the mission's science objectives. The caveat in relation to its sampling requirements is that SMOS will have a somewhat reduced sensitivity when compared to conventional radiometers. The SMOS satellite was launched successfully on November 2, 2009.

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The SMOS Mission: New Tool for Monitoring Key Elements ofthe Global Water Cycle

Soil compaction is one of the major problems facing modern agriculture. Overuse of machinery, intensive cropping, short crop rotations, intensive grazing and inappropriate soil management leads to compaction. Soil compaction occurs in a wide range of soils and climates. It is exacerbated by low soil organic matter content and use of tillage or grazing at high soil moisture content. Soil compaction increases soil strength and decreases soil physical fertility through decreasing storage and supply of water and nutrients, which leads to additional fertiliser requirement and increasing production cost. A detrimental sequence then occurs of reduced plant growth leading to lower inputs of fresh organic matter to the soil, reduced nutrient recycling and mineralisation, reduced activities of micro-organisms, and increased wear and tear on cultivation machinery. This paper reviews the work related to soil compaction, concentrating on research that has been published in the last 15 years. We discuss the nature and causes of soil compaction and the possible solutions suggested in the literature. Several approaches have been suggested to address the soil compaction problem, which should be applied according to the soil, environment and farming system. The following practical techniques have emerged on how to avoid, delay or prevent soil compaction: (a) reducing pressure on soil either by decreasing axle load and/or increasing the contact area of wheels with the soil; (b) working soil and allowing grazing at optimal soil moisture; (c) reducing the number of passes by farm machinery and the intensity and frequency of grazing; (d) confining traffic to certain areas of the field (controlled traffic); (e) increasing soil organic matter through retention of crop and pasture residues; (f) removing soil compaction by deep ripping in the presence of an aggregating agent; (g) crop rotations that include plants with deep, strong taproots; (h) maintenance of an appropriate base saturation ratio and complete nutrition to meet crop requirements to help the soil/crop system to resist harmful external stresses.

Soil compaction in cropping systems: A review of the nature, causes and possible solutions

http://files.aprendiendoquimica7.webnode.com.co/200000006-1247d13423/Limousin,%20G%20et%20al.%20Sorption%20Isotherms%20A%20review%20on%20Physical%20Bases,%20modeling%20and%20measurement.pdf

Sorption isotherms: A review on physical bases, modeling and measurement

Time domain reflectometry (TDR) has been developed to an operational level for the measurement of soil water content during the past decade. Because it is able to provide fast, precise and nondestructive in situ measurements, it has become an alternative to the neutron scattering method, in particular for monitoring water content under field conditions. One of the major disadvantages of the neutron scattering technique is that, due to the relatively high sensitivity of the signal to factors other than water content, site-specific calibration is usually required. In this paper a calibration curve for the TDR method is presented which is not restricted to specific soil conditions. The calibration is based on the dielectric mixing model of Dobson et al. (1985). Measurements of volumetric water content and dielectric number at eleven different field sites representing a wide range of soil types were used to determine the parameter of the model by weighted nonlinear regression. The uncertainty (root mean square error) of water content values calculated with the optimized calibration curve was estimated not to exceed 0.013 cm3/cm3. This value is comparable to the precision of the thermogravimetric method. From a sensitivity analysis it was determined that the temperature dependence of the TDR signal may have to be corrected to obtain optimum accuracy.

Calibration of time domain reflectometry for water content measurement using a composite dielectric approach

Flow pathways of water and solutes in soils form distinct patterns, which are not a priori predictable. Macropore structure is a prime cause, but other factors, such as differing initial or boundary conditions, may also predispose a soil to produce bypassing of infiltrating water. This study was conducted to assess the flow pathways of water in different soils and to investigate the effect of initial water content on the flow pattern. Dye-tracing experiments were carried out at 14 different field sites. The sites represent a good portion of soils used for agricultural crop production in Switzerland. Each site consisted of two 1.4 by 1.4 m plots, one of which had been covered with a plastic roof for two months before the experiment to achieve different initial water contents. Forty millimeters of water containing the dye Brilliant Blue FCF (C.I. Food Blue 2) were applied within 8 hours onto the plots with a sprinkling apparatus. One day after irrigation the plots were excavated, and the stained pattern was examined on a vertical 1 by l m soil profile. The spatial structure of flow patterns showed remarkable differences. In most soils, water bypassed the soil matrix. In some soils, dye penetrated beyond l m depth, whereas in others it remained in the top 50 cm. Structured soils were more prone to produce bypass flow, deep dye penetration, and pulse splitting than nonstructured soils. The initial water content had a less pronounced effect in some soils and no effect in others.

Susceptibility of soils to preferential flow of water : a field study

Phosphorus is the limiting factor for primary production in most freshwater ecosystems. In many areas, diffuse P losses from intensively cultivated land cause severe eutrophication of surface waters. We investigated the P export from two drainage systems under intensively used grassland in a catchment of the Swiss Plateau. Flow rate and nutrient concentrations were measured with a high temporal resolution during discharge events. During most flow peaks, P concentrations strongly increased with increasing flow rates. Concentrations of soluble-reactive P (SRP) reached up to 155 μmol L -1 . Phosphorus was mainly transported as soluble-reactive and particulate P. Organic P compounds, as well as P associated with colloids between 0.05 and 0.45 μm in effective diameter, were of minor importance. Estimated P loads from the drainage systems were 227 g SRP ha -1 within a period of 2.5 mo at site I and 1290 g ha -1 during 6 mo at site II. Estimation uncertainty was large (±21 and ±36% for the two sites, respectively) due to the weak correlation between discharge and concentration for all data from a given site. Water-extractable P in the soil was concentrated in the uppermost layer of the profiles or, for short periods after spreading of manure, deposited on the vegetation. The discharge-concentration relationship indicated that P was transported through preferential flow paths extending from close to the surface to the drains. Sprinkling experiments with a blue dye confirmed this conclusion. At one site, we observed preferential flow in a downhill direction within the saturated zone.

Preferential transport of phosphorus in drained grassland soils

Dyes are widely used to stain the travel paths of water and solutes in soils. Brilliant Blue FCF (C.I. Food Blue 2) is a valuable dye tracer for visualizing water flow patterns. Because this dye is nontoxic, it is particularly suited for field use. Depending on pH, the dye is either neutral or dissociates to a mono- or bivalent anion. The water solubility is 200 kg m -3 . In this study, properties of the dye that characterize the adsorbing behavior in soil were determined. Batch adsorption experiments were carried out in the laboratory, and a field experiment was conducted to compare the mobility of Brilliant Blue FCF with that of I - and Br - . The batch studies gave distribution coefficients K d of 0.19, 3.00, and 5.78 dm 3 kg -1 for three different soils. The results of the batch studies suggest that the dye forms ion pairs with Ca 2+ . The field experiment showed that the dye is retarded compared with the conservative tracer Br - . A comparison between Brilliant Blue FCF and I - analyzed with the iodide-starch method resulted in a relative retardation of 1.2 Brilliant Blue FCF compared with I -

Tracer Characteristics of Brilliant Blue FCF

In this study, we estimated whether changes in hydrological pathwaysduring storms could explain the large temporal variations of dissolvedorganic carbon (DOC) and nitrogen (DON) in the runoff of threecatchments: a forest and a grassland sub-catchment of 1600m2 delineated by trenches, and a headwater catchment of 0.7km2. The average annual DOC export from the sub-catchments was 185 kg DOCha−1 y−1 for the forest, 108 kg DOCha−1 y−1 for the grassland and 84 kgDOC ha−1 y−1 for the headwatercatchment. DON was the major form of the dissolved N in soil and streamwater. DON export from all catchments was approximately 6 kg Nha−1 y−1, which corresponded to 60% ofthe total N export and to 50% of the ambient wet N deposition. DOC andDON concentrations in weekly samples of stream water were positivelycorrelated with discharge. During individual storms, concentrations andproperties of DOC and DON changed drastically. In all catchments, DOCconcentrations increased by 6 to 7 mg DOC l−1 comparedto base flow, with the largest relative increment in the headwatercatchment (+350%). Concentrations of DON, hydrolysable amino acids, andphenolics showed comparable increases, whereas the proportion ofcarbohydrates in DOC decreased at peak flow. Prediction of DOC and DONconcentrations by an end-member mixing analysis (EMMA) on the base ofinorganic water chemistry showed that changes in water flow pathslargely explained these temporal variability. According to the EMMA, thecontribution of throughfall to the runoff peaked in the initial phase ofthe storm, while water from the subsoil dominated during base flow only.EMMA indicated that the contribution of the DOC and DON-rich topsoil washighest in the later stages of the storm, which explained the highestDOC and DON concentrations as the hydrograph receded. Discrepanciesbetween observed and predicted concentrations were largest for thereactive DOC compounds such as carbohydrates and phenolics. Theyoccurred at base flow and in the initial phase of storms. This suggeststhat other mechanisms such as in-stream processes or a time-variantrelease of DOC also played an important role.

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Hannes Flühler

Papers

Calibration of time domain reflectometry for water content measurement using a composite dielectric approach

Susceptibility of soils to preferential flow of water : a field study

Preferential transport of phosphorus in drained grassland soils

Tracer Characteristics of Brilliant Blue FCF

Export of dissolved organic carbon and nitrogen from Gleysol dominated catchments – the significance of water flow paths