H
Haolin Yin
Researcher at University of Pennsylvania
Publications - 24
Citations - 1910
Haolin Yin is an academic researcher from University of Pennsylvania. The author has contributed to research in topics: Aryl & Catalysis. The author has an hindex of 16, co-authored 22 publications receiving 1546 citations.
Papers
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Journal ArticleDOI
The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides
Haolin Yin,Yi Jin,Jerald E. Hertzog,Jerald E. Hertzog,Kimberly C. Mullane,Patrick J. Carroll,Brian C. Manor,Jessica M. Anna,Eric J. Schelter +8 more
TL;DR: The hexachlorocerate(III) anion, [CeIIICl6]3-, was found to be a potent photoreductant in acetonitrile solution with an estimated excited-state reduction potential of -3.45 V versus Cp2Fe0/+.
Journal ArticleDOI
Understanding and Controlling the Emission Brightness and Color of Molecular Cerium Luminophores.
Yusen Qiao,Dumitru-Claudiu Sergentu,Haolin Yin,Alexander V. Zabula,Thibault Cheisson,Alex McSkimming,Brian C. Manor,Patrick J. Carroll,Jessica M. Anna,Jochen Autschbach,Eric J. Schelter +10 more
TL;DR: The results establish a comprehensive structure-luminescence model for molecular cerium(III) luminophores in terms of both quantum yields and colors and provide a clear basis for the design of tunable, molecular, cerium-based, luminescent materials.
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Anomalous one-electron processes in the chemistry of uranium nitrogen multiple bonds.
TL;DR: Comparison of the U(VI)(═NSiMe3)X[N(Si me3)2]3, X = Cl, Br, complexes with the previously reported U( VI)OX[N (SiMe 3)2)3,X = Cl-Br, complexes suggested that the donor strength of the trimethylsilylimido ligand is comparable to the oxo ligand.
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Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Umpolung 1,4-Addition of Aryl Iodides to Enals
TL;DR: A (terpy)Pd/NHC cooperative catalyzed umpolung 1,4-addition of aryl iodides to enals to generate various bioactive β,β-diaryl propanoate derivatives is described.
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A New Class of Organocatalysts: Sulfenate Anions
TL;DR: Mechanistic studies support the intermediacy of sulfenate anions, and the deprotonated sulfoxide was determined to be the resting state of the catalyst.