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Showing papers by "Heinz Gornitzka published in 2014"

Journal Article•DOI•
Synthesis, structures, and selective toxicity to cancer cells of gold(I) complexes involving N-heterocyclic carbene ligands.

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Luca Boselli1, Isabelle Ader1, Maëlle Carraz2, Catherine Hemmert3, Catherine Hemmert1, Olivier Cuvillier1, Olivier Cuvillier3, Heinz Gornitzka1, Heinz Gornitzka3 •
University of Toulouse1, Institut de recherche pour le développement2, Centre national de la recherche scientifique3
06 Oct 2014-European Journal of Medicinal Chemistry
TL;DR: New gold(I) complexes containing two 1-[2-(diethylamino)ethyl]imidazolydene ligands have been synthesized and characterized and the most active complex demonstrated a potent selectivity for cancer cells.

43 citations

Journal Article•DOI•
Remote Stereocontrol in the Synthesis of Acyclic 1,4-Diols and 1,4-Aminoalcohols from 2-Sulfinyl Dienes

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Roberto Fernández de la Pradilla1, Marina Velado1, Ignacio Colomer1, Carmen Simal1, Alma Viso1, Heinz Gornitzka2, Catherine Hemmert2 •
Spanish National Research Council1, Centre national de la recherche scientifique2
24 Sep 2014-Organic Letters
TL;DR: The highly diastereoselective conjugate addition of alcohols and amines (RXH) to enantiopure 2-sulfinyl dienes renders transient allylic sulfoxides which undergo sulfoxide-Sulfenate rearrangement and sulfenate cleavage providing 2-ene-1,4-diols and 2-enes-1-4-aminoalcohols with up to 99:1 dr.

9 citations

Journal Article•DOI•
Comparison of reactivity of phosphagermaallene Tip(t-Bu)GeCPMes* towards sulfur ylides

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Tibor-Gabor Kocsor1, Tibor-Gabor Kocsor2, Noémi Deak1, Noémi Deak2, Dumitru Ghereg1, Gabriela Nemes2, Jean Escudié1, Heinz Gornitzka3, Heinz Gornitzka1, Sonia Ladeira1, Annie Castel1 •
University of Toulouse1, Babeș-Bolyai University2, Centre national de la recherche scientifique3
01 Apr 2014-Journal of Organometallic Chemistry
TL;DR: In this article, a single crystal X-ray structural analysis was carried out on Phosphagermaallene and dimethyloxosulfoniummethylide (Me2S(O) CH2).

4 citations