H
Henri Rudler
Researcher at Pierre-and-Marie-Curie University
Publications - 174
Citations - 2082
Henri Rudler is an academic researcher from Pierre-and-Marie-Curie University. The author has contributed to research in topics: Carbene & Ketene. The author has an hindex of 25, co-authored 174 publications receiving 2061 citations. Previous affiliations of Henri Rudler include Cergy-Pontoise University & Centre national de la recherche scientifique.
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Reaction of Nucleophiles with Alkoxycarbene Complexes of Chromium: A General Access to Polycyclic Substituted Butenolides.
TL;DR: A series of substituted butenolides have been obtained either by reacting alkynylalkoxycarbene complexes 3 with simple nucleophiles such as metal hydrides, metal alkoxides and metal alkyls, or by reacting simple alkoxy carbene complexes 6 with more elaborate nucleophilic such as the metal alkynolates or metal alkynyls.
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Umwandlung von olefinen, der einfluss von wolframhydriden und eine neue form der spaltung von alkyl-wolfram-bindungen
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Aminocarbene Complexes of Chromium and Molybdenum: Initiators for Cascade Reactions with Alkynes Leading to New Heterocyclic Compounds via Nitrogen Ylides
Henri Rudler,Max Audouin,Evelyne Chelain,B. Denise,Régis Goumont,A. Massoud,Andrée Parlier,Annie Pacreau,M. Rudler,R. Yefsah,Cecilio Alvarez,F. Delgado-Reyes +11 more
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Substituted Cyclopropylamines from Pyridinium Ylide: Complexes of Pentacarbonyl Tungsten and Enamines.
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First Intramolecular Alkyne-CO Insertion Reactions in Aminocarbene Complexes of Chromium: Formation of Condensed Heterocycles Following Extensive Hydrogen Migrations.
TL;DR: The chromium carbonyl complex (I) is converted into the aminocarbene complex (IV) which undergoes demetalation and cyclization upon thermolysis, forming the fused pyridine derivative (V).