H
Henri Rudler
Researcher at Pierre-and-Marie-Curie University
Publications - 174
Citations - 2082
Henri Rudler is an academic researcher from Pierre-and-Marie-Curie University. The author has contributed to research in topics: Carbene & Ketene. The author has an hindex of 25, co-authored 174 publications receiving 2061 citations. Previous affiliations of Henri Rudler include Cergy-Pontoise University & Centre national de la recherche scientifique.
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Chimie organometallique : IX. Reaction du tungstadiphenylcarbene avec les ethers d'enols cycliques
TL;DR: In this article, the ring size in the enol ether is the determining factor for the cyclopentanone derivative's ring-opened product (CO)5WC(OEt) which has been isolated and characterized.
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Carbene complexes in organic synthesis: a new tungstacarbene-promoted alkyne insertion–olefin cyclopropanation reaction
TL;DR: Carbene complexes of tungsten, bearing a co-ordinated double bond two carbons away from the carbene function, react with alkynes to give, after insertion of the alkyne, bicyclo[4.1.0]heptane derivatives as a result of cyclopropanation of the double bond by the newly formed carbene complex as mentioned in this paper.
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Synthese et etude structurale d'un complexe mononucleaire du tungstene portant a la fois un groupement alkylidene et une double liaison
Cecilio Alvarez Toledano,Jacques Levisalles,M. Rudler,Henri Rudler,Jean-Claude Daran,Yves Jeannin +5 more
TL;DR: In this paper, an X-ray structure of complex 14 shows that the alkylidene function and the coordinated double bond are perpendicular to each other, which is a result of coordination of the double bonds of complex 6 and 13.
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Synthesis and x-ray structures of some homonuclear μ-alkylidenetungsten complexes
TL;DR: In this paper, the first heteroatom-substitued μ-alkylidene complexes of tungsten were synthesized, starting from conjugated Fischer-typ carbene complexes (CO) 5 WC(OR)CH-CHR, and an X-ray diffraction study has revealed the presence of five CO groups on each metal center.
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Meta, para and meta, ortho double exo nucleophilic additions of trimethylsilylester enolates derived from saturated and unsaturated carboxylic acids to tricarbonylchromium complexes of aryl ethers: dearomatizing cyclization to lactones
Henri Rudler,Virginie Comte,Eva Garrier,Eva Garrier,Moncef Bellassoued,Evelyne Chelain,Jacqueline Vaissermann +6 more
TL;DR: In this article, the influence of the nature of substituents on the ketene acetals, of the oxidant and of the ester enolates on the course of the reaction has been established and discussed.