H
Henri Rudler
Researcher at Pierre-and-Marie-Curie University
Publications - 174
Citations - 2082
Henri Rudler is an academic researcher from Pierre-and-Marie-Curie University. The author has contributed to research in topics: Carbene & Ketene. The author has an hindex of 25, co-authored 174 publications receiving 2061 citations. Previous affiliations of Henri Rudler include Cergy-Pontoise University & Centre national de la recherche scientifique.
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A Major Breakthrough in the Use of Alkoxycarbene Complexes of Chromium and Tungsten for the Synthesis of Elaborate Organic Compounds: Dihydropyridine Induced Reductions and Cascade Insertion Reactions
Henri Rudler,Andrée Parlier,Thomas Durand-Réville,Blanca Martı́n-Vaca,Max Audouin,Eva Garrier,Victor Certal,Jacqueline Vaissermann +7 more
TL;DR: Alkoxy (alkyl) carbene complexes of tungsten and chromium react with dihydropyridine and N-methyldihydroid-phyridine to give respectively pyridinium ylid complexes.
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New metal carbenes as initiators of the polymerization of alkynes
TL;DR: In this article, a complexe du tungstene pour polymeriser, diverses alcynes et en particulier l'heptyne dans l'exane a 20°C.
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Transition-metal catalyzed synthesis of δ-hydroxy-γ-lactones from bis(trimethylsilyl) ketene acetals and allylic acetates via γ-unsaturated carboxylic acids. Comments on the formation of α-cyclopropyl carboxylic acids
Henri Rudler,Paul Harris,Andrée Parlier,Frédéric Cantagrel,Bernard Denise,Moncef Bellassoued,Jacqueline Vaissermann +6 more
TL;DR: The mechanism of the formation of cyclopropanic acids has been discussed in this paper, where the structure of two of these lactones has been established by X-ray analysis.
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Reactivity of N-disubstituted aminocarbene complexes of chromium: nitrogen to carbon migration of the benzyl and allyl groups following alkyne insertions
Bernard Denise,Regis Goumont,Andrée Parlier,Henri Rudler,Jean-Claude Daran,Jacqueline Vaissermann +5 more
TL;DR: The structures of (CO) 5 -CrC(CH 3 )N(CH 2 Ph)CH 3 (3 Z ) (R 0.031 R w 0.030) and of the chromium tricarbonyl complex of the pyrrolinone as discussed by the authors, which was determined by the X-ray diffraction.
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Overall “Pseudocationic” Trifluoromethylation of Dihydropyridines with Triflic Anhydride†
TL;DR: To compare the two activation procedures, with methyl chloroformate or triflic anhydride, a series of dihydropyridines subsituted by a triflyl group on the nitrogen atom were synthesized, leading to the discovery of a new, unexpected transformation of these dihydrocarbonidines.