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Hervé Cailleau

Researcher at University of Rennes

Publications -  125
Citations -  3442

Hervé Cailleau is an academic researcher from University of Rennes. The author has contributed to research in topics: Phase transition & Phase (matter). The author has an hindex of 32, co-authored 121 publications receiving 3204 citations. Previous affiliations of Hervé Cailleau include KEK & Centre national de la recherche scientifique.

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Laser-induced ferroelectric structural order in an organic charge-transfer crystal

TL;DR: Direct observation by x-ray diffraction of a photoinduced paraelectric-to-ferroelectric structural phase transition using monochromatic 100-picosecond synchrotron pulses in tetrathiafulvalene-p-chloranil indicates structural changes at the molecular level.
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Symmetry breaking and structural changes at the neutral-to-ionic transition in tetrathiafulvalene-p-chloranil.

TL;DR: The structural aspect of the temperature-induced neutral-to-ionic transition in the mixed-stack charge-transfer complex TTF-p-chloranil is directly analyzed using results obtained from neutron-scattering experiments as discussed by the authors.
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Structural phase transition in polyphenyls. IV. Double‐well potential in the disordered phase of p‐terphenyl from neutron (200 K) and X‐ray (room‐temperature) diffraction data

TL;DR: KITAIGORODSKY, A. I., HOTSYANOVA, T. L. as discussed by the authors, RIETVELD, H. M. and STRUCHKOV, YU.
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Elastically driven cooperative response of a molecular material impacted by a laser pulse.

TL;DR: A self-amplified responsiveness in a spin-crossover material during its delayed volume expansion is demonstrated and it is shown that elastically driven cooperativity triggered by a light pulse offers an efficient route towards the generation and stabilization of photoinduced phases in many volume-changing materials.
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Sequential Activation of Molecular Breathing and Bending during Spin-Crossover Photoswitching Revealed by Femtosecond Optical and X-Ray Absorption Spectroscopy.

TL;DR: Combined femtosecond x-ray absorption performed at LCLS X-FEL and optical spectroscopy reveal that the structural stabilization of the photoinduced high-spin state results from a two step structural trapping.