https://arpi.unipi.it/bitstream/11568/798598/2/polacco%20798598.pdf

A review of the fundamentals of polymer-modified asphalts: Asphalt/polymer interactions and principles of compatibility

Rheological, microscopic, and chemical characterization of the rejuvenating effect on asphalt binders

As a widely accepted concept, bitumen consists of four fractions that can be distinguished by their polarity. Highly polar asphaltene micelles are dispersed in a viscous phase of saturates, aromatics and resins (maltene phase). Different concentrations of asphaltenes in the bitumen result in a range of mechanical response properties. In an interdisciplinary study the impact of the maltene phase and asphaltenes on the linear viscoelastic behavior and the microstructure of bitumen were analyzed by creep recovery testing in a DSR and by atomic force microscopy (AFM). Therefore, bitumen was separated into the maltene and asphaltene fractions and artificial bitumen samples with different, pre-defined asphaltene concentrations were produced and investigated. It was found that the artificially produced, precipitated bitumen samples can be regarded as a representative, bitumen-like material in terms of mechanical behavior and microstructure. Asphaltenes play an important role in the typical viscoelastic behavior of bitumen being mainly responsible for stiffness and elasticity. Also, their concentration appears to be correlated to the occurrence and shape of the bee-like inclusions which can be typically observed by AFM.

/pdf/impact-of-maltene-and-asphaltene-fraction-on-mechanical-30asklu3v5.pdf

Impact of maltene and asphaltene fraction on mechanical behavior and microstructure of bitumen

Influence of short and long term aging on chemical, microstructural and macro-mechanical properties of recycled asphalt mixtures

Surface microstructure of bitumen characterized by atomic force microscopy.

In the past years a wide discussion has been held among asphalt researchers regarding the existence and interpretation of observed microstructures on bitumen surfaces. To investigate this, the RILEM technical committee on nano bituminous materials 231-NBM has conducted a round robin study combining differential scanning calorimetry (DSC) and Atomic Force Microscopy (AFM). From this, methods for performing DSC and AFM tests on bitumen samples and determination of the influence of wax on the observed phases, taking into account thermal history, sample preparation and annealing procedure, are presented and critically discussed. DSC is used to measure various properties and phenomena that indicate physical changes such as glass transition temperature (T g) and phase transition such as melting and crystallization. In the case of existence of wax, either natural or synthetic, it can further indicate the melting point of wax, that could be used to determine wax content. The results from seven laboratories show that T g temperatures obtained from the heating scans are more repeatable and easier to obtain in comparison to the cooling scans. No significant difference was noted for T g's obtained from the first and second heating scans. AFM is an imaging tool used to characterize the microstructures on a bituminous surface. Using AFM three phases in the materials with wax could be distinguished. The changes in the phases observed with AFM for increases in temperature were correlated with the DSC curve, and it could be established that the so called "Bee" structure disappeared around the melting peak in the DSC curve. Thus, this research has confirmed the relation between the microstructures on a bitumen surface and the wax content. cop. 2013 RILEM.

/pdf/laboratory-investigation-of-bitumen-based-on-round-robin-dsc-3azr5j97j4.pdf

Laboratory investigation of bitumen based on round robin DSC and AFM tests

This paper presents the results of a round robin test (RRT) on binder fatigue, with data received from 11 participating laboratories. Most data were obtained with a Dynamic Shear Rheometer (DSR) equipment, one laboratory used a tension-compressiontest. In a first stage, the RRT consisted of three binders, two unmodified binders and onepolymer modified binder. These three binders had almost the same stiffness level at the testing conditions, 10°C and 10 Hz. Fatigue tests were conducted at three strain levels, and each strain level was measured in three repeats. For each test it was asked to follow the small strain stiffness during an equilibration time of 30 minutes. A second stage of this RRT including two more binders is foreseen. The same three binders were also tested in two and in four point bending mix fatigue tests. The analysis was separated into two parts, in a first part the repeatability and reproducibility of the small strain equilibrium stiffness was evaluated and in a second part the fatigue data were analyzed. Small strain stiffness data showed that the repeatability and reproducibility of G* is still not very high, and possible reasons are under evaluation. The analysis of the fatigue data showed that the overall reproducibility was not good. But when all participants that did in some way not follow the preparation procedure or that had problems with recording, were excluded, it was found that for 6 of the participating laboratories the fatigue properties gave good repeatability and reproducibility levels, for the two unmodified binders in this study. Each laboratory could distinguish the better fatigue life of the polymer modified binder compared to the unmodified binders as was also confirmed by mixture tests. This shows that the binder behavior plays an important role in the fatigue behavior of the mix, and that a binder test should be able to evaluate this role. The binder fatigue test can be used as a surrogate test for mixture fatigue, implying considerable time savings in sample preparation, however the testing of the binders is still time consuming.

Hilde Soenen

Papers

Laboratory investigation of bitumen based on round robin DSC and AFM tests

Binder fatigue properties and the results of the Rilem round robin test