A converter containing a NOx absorbing and reducing catalyst is disposed in the exhaust passage of an internal combustion engine. The upstream half portion (portion of the inlet side) of the substrate of the NOx absorbing and reducing catalyst in the converter carries the oxygen storage component that absorbs oxygen in the exhaust gas when the air-fuel ratio of the exhaust gas is lean and releases the absorbed oxygen when the air-fuel ratio of the exhaust gas flowing in is rich in addition to carrying the NOx absorbing and reducing catalyst. After NOx is absorbed by the NOx absorbing and reducing catalyst as a result of operating the engine at a lean air-fuel ratio, the engine is operated at a rich air-fuel ratio, so that NOx is released from the NOx absorbing and reducing catalyst and is purified by reduction. Here, oxygen is released from the oxygen storage component carried by the upstream half portion of the substrate and is reacted with the H 2 and CO components in the exhaust gas, so that the temperature of the NOx absorbing and reducing catalyst is raised within short periods of time due to the heat of reaction. Therefore, the catalyst exhibits increased activity and the NOx absorbing and reducing catalyst exhibits improved NOx purification capability.

Exhaust gas purification device for an internal combustion engine

An air-fuel ratio control system for an internal combustion engine includes a LAF sensor and an O2 sensor arranged in an exhaust pipe at respective locations upstream and downstream of a catalytic converter. A desired air-fuel ratio coefficient used in calculating an amount of fuel supplied to the engine is calculated based on operating conditions of the engine, and corrected based on output from the O2 sensor. The air-fuel ratio of a mixture supplied to the engine is feedback-controlled to a stoichiometric air-fuel ratio based on the corrected desired air-fuel ratio coefficient. When the output from the O2 sensor falls within a predetermined range, the desired air-fuel ratio coefficient is not corrected, but held at an immediately preceding value thereof.

Air-fuel ratio control system for internal combustion engines

According to one embodiment, a nonaqueous electrolyte battery is provided. The battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes lithium iron phosphate having an olivine structure as positive electrode active material. The negative electrode includes lithium titanate having a spinel structure and a monoclinic β-type titanium complex oxide as a negative electrode active material.

Nonaqueous electrolyte battery and battery pack

A high capacity lithium secondary battery with excellent safety is provided by suppressing expansion of a negative electrode active material during charge and increasing the content of a heat-resistant resin in a separator relative to conventional one. The lithium secondary battery includes: a negative electrode active material that comprises compound particles containing at least one metal element selected from the group consisting of Si, Sn, Al, and Zn; and a separator that has a first porous layer comprising polyolefin and a second porous layer comprising a heat-resistant resin. The separator contains 10 to 60 parts by weight of the second porous layer per 100 parts by weight of the first porous layer.

Lithium Secondary Battery

A system for controlling fuel metering in an internal combustion engine using a fluid dynamic model with the quantity of throttle-past air being determined therefrom. Based on the observation that the difference between the steady-state engine operating condition and the transient engine operating condition can be described as the difference in the effective throttle opening areas, the quantity of fuel injection is determined from the product of the ratio between the area and its first-order lag value and the quantity of fuel injection under the steady-state engine operating condition obtained by mapped data retrieval and by subtracting the quantity of correction corresponding to the quantity of chamber-filling air. A pseudo-manifold pressure is estimated and is used for calculating the effective throttle opening area and its first lag value. The pseudo-manifold pressure is corrected by atmospheric pressure, engine coolant water temperature, etc., so as to enhance estimation accuracy.

Fuel metering control system for internal combustion engine

In an exhaust gas purification device for an internal combustion engine, a NOX occluding and reducing catalyst is disposed in the exhaust gas passage of an engine. The NOX occluding and reducing catalyst absorbs NOX in the exhaust gas when the air-fuel ratio of the exhaust gas is at a lean air-fuel ratio and releases and reduces NOX when the air-fuel ratio of the exhaust gas is at a rich air-fuel ratio. The air-fuel ratio of the exhaust gas flowing out from the catalyst is detected by an air-fuel ratio sensor disposed in the exhaust gas passage downstream of the catalyst. When the air-fuel ratio of the exhaust gas flowing into the catalyst is changed from a rich air-fuel ratio to a lean air-fuel ratio, the air-fuel ratio of the exhaust gas flowing out from the catalyst stays at a stoichiometric air-fuel ratio before it changes to a lean air-fuel ratio. The length of the period in which the air-fuel ratio of the exhaust gas flowing out from the catalyst stays at a stoichiometric air-fuel ratio corresponds to the magnitude of the ability of the NOX occluding and reducing catalyst as a reducing catalyst. Thus, by measuring the length of the stoichiometric air-fuel ratio period of the exhaust gas flowing out from the NOX occluding and reducing catalyst, the ability of the NOX occluding and reducing catalyst as a reducing catalyst can be precisely evaluated.

An apparatus for detecting abnormal air-fuel ratio variation among cylinders of a multi-cylinder internal combustion engine (1) according to the invention includes: a catalyst element (11) that oxidizes hydrogen contained in exhaust gas to remove the hydrogen; a first air-fuel ratio sensor (17) that detects an air-fuel ratio of exhaust gas that has not passed through the catalyst element (11); a second air-fuel ratio sensor (18) that detects an air-fuel ratio of exhaust gas that has passed through the catalyst element (11); and a unit (20) that determines whether abnormal air-fuel ratio variation among the cylinders has occurred based on an amount by which a value detected by the second air-fuel ratio sensor (18) is leaner than a value detected by the first air-fuel ratio sensor (17)

Apparatus and method for detecting abnormal air-fuel ratio variation among cylinders of multi-cylinder internal combustion engine

An upstream side catalyst and a downstream side catalyst are disposed in an exhaust passage. A first oxygen sensor is disposed between these two catalysts and a second oxygen sensor is disposed downstream of the downstream side catalyst. The air-fuel ratio is forcibly oscillated and the oxygen storage capacity of the upstream side catalyst is detected. Deterioration of the upstream side catalyst is then detected based on whether this oxygen storage capacity is larger than a predetermined value. The forced oscillation of the air-fuel ratio is performed only when the oxygen storage state of the downstream side catalyst is appropriate.

Catalyst deterioration detecting apparatus and method

In an air-fuel ratio feedback system including a single air-fuel ratio sensor downstream of or within a three-way catalyst converter, a coarse-adjusting term is calculated integrally in accordance with the output of the air-fuel ratio sensor, and a fine-adjusting term is calculated differentially at every reversion of the actual air-fuel ratio in accordance with the coarse-adjusting term and the fine-adjusting term. When a time of the reversion of the output of the air-fuel ratio sensor is small, the calculation of the coarse-adjusting term is prohibited.

Air-fuel ratio feedback control system having a single air-fuel ratio sensor downstream of a three-way catalyst converter

In order to study a diffusive behavior of Li+ in Li intercalated graphites, we have measured muon spin relaxation (mu+SR) spectra for C6Li and C12Li synthesized with an electrochemical reaction bet ...

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Hiroshi Sawada

Papers

Exhaust gas purification device for an internal combustion engine

Apparatus and method for detecting abnormal air-fuel ratio variation among cylinders of multi-cylinder internal combustion engine

Catalyst deterioration detecting apparatus and method

Air-fuel ratio feedback control system having a single air-fuel ratio sensor downstream of a three-way catalyst converter

Li-ion diffusion in Li intercalated graphite C6Li and C12Li probed by μ+SR.