Iman G. Khazal

TL;DR: It is shown here that a metal complex can facilitate the reversible interaction of para-hydrogen with a suitable organic substrate such that up to an 800-fold increase in proton, carbon, and nitrogen signal strengths are seen for the substrate without its hydrogenation.

TL;DR: Parahydrogen induced polarization (PHIP) based on the hydride ligands of 2 and 3 is transferred efficiently to the 15N nuclei of the bound pyridine ligand by suitable insensitive-nuclei-enhanced-by-polarization-transfer (INEPT) based procedures.

TL;DR: In this article, the authors describe how the complexes Ir(COD)(NHC)Cl [NHC = IMes, SIMes, IPr, SIPr, ICy, IMe and ImMe2NPri2] provide significant insight into the catalytic process that underpins the hyperpolarization method signal amplification by reversible exchange.

TL;DR: A series of platinum metal silyl hydride complexes, such as cis-Pt(PCy3)2(H)(SiR2R‘) as mentioned in this paper, have been characterized by X-ray crystallography at −100 °C.

TL;DR: In this paper, structural and electronic properties of a library of transition-metal-coordinated alkyne and vinylidene tautomers in different coordination environments were investigated with a view to demonstrating the feasibility and utility of multivariate computational screening of organometallic catalysts.