J
J. Paige Phillips
Researcher at University of Southern Mississippi
Publications - 23
Citations - 957
J. Paige Phillips is an academic researcher from University of Southern Mississippi. The author has contributed to research in topics: Fullerene & Nitride. The author has an hindex of 15, co-authored 23 publications receiving 885 citations. Previous affiliations of J. Paige Phillips include Virginia Tech.
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Journal ArticleDOI
A Distorted Tetrahedral Metal Oxide Cluster inside an Icosahedral Carbon Cage. Synthesis, Isolation, and Structural Characterization of Sc4(μ3-O)2@Ih-C80
Steven Stevenson,Mary A. Mackey,Melissa A. Stuart,J. Paige Phillips,Michael L. Easterling,Christopher J. Chancellor,Marilyn M. Olmstead,Alan L. Balch +7 more
TL;DR: The remarkably large cluster Sc4(mu3-O)2 has been obtained trapped inside an Ih-C80 cage by conducting the vaporization of graphite rods doped with copper(II) nitrate and scandium(III) oxide in an electric arc under a low pressure helium atmosphere with an added flow of air.
Journal ArticleDOI
A seven atom cluster in a carbon cage, the crystallographically determined structure of Sc4(μ3-O)3@Ih-C80
Brandon Q. Mercado,Marilyn M. Olmstead,Christine M. Beavers,Michael L. Easterling,Steven Stevenson,Mary A. Mackey,Curtis E. Coumbe,Joshua D. Phillips,J. Paige Phillips,Josep M. Poblet,Alan L. Balch +10 more
TL;DR: The tetrahedral array of four scandium atoms with oxygen atoms capping three of the four faces found in Sc(4)(mu(3)-O)(3)@I(h)-C(80) is the largest cluster isolated to date inside a fullerene cage.
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Poly(perfluoroalkylation) of metallic nitride fullerenes reveals addition-pattern guidelines: synthesis and characterization of a family of Sc3N@C80(CF3)n (n = 2-16) and their radical anions.
Natalia B. Shustova,Dmitry V. Peryshkov,Igor V. Kuvychko,Yu-Sheng Chen,Mary A. Mackey,Curtis E. Coumbe,David T. Heaps,Bridget S. Confait,Thomas Heine,J. Paige Phillips,Steven Stevenson,Lothar Dunsch,Alexey A. Popov,Steven H. Strauss,Olga V. Boltalina +14 more
TL;DR: Facile further functionalizations via cycloadditions or radical additions were achieved for trifluoromethylated Sc(3)N@C(80) making them attractive versatile platforms for the design of molecular and supramolecular materials of fundamental and practical importance.
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Rapid Removal of D5h Isomer Using the “Stir and Filter Approach” and Isolation of Large Quantities of Isomerically Pure Sc3N@C80 Metallic Nitride Fullerenes
Steven Stevenson,Mary A. Mackey,Curtis E. Coumbe,J. Paige Phillips,Bevan Elliott,Luis Echegoyen +5 more
TL;DR: A rapid (13 h) removal of contaminant D5h Sc3N@C80 isomer is reported and the subsequent isolation of large quantities of isomerically pure Ih Sc 3N @C80 metallofullerenes using a diaminosilica “Stir and Filter Approach” process is reported.
Journal ArticleDOI
Synthesis and purification of a metallic nitride fullerene bisadduct: exploring the reactivity of Gd3N@C80.
Steven Stevenson,Ryan R. Stephen,Thomas M. Amos,Veronica R. Cadorette,Jonathan E. Reid,J. Paige Phillips +5 more
TL;DR: Results demonstrate that a bisadduct can be prepared in an isolable yield for this MRI precursor MNF, a significant finding as, to date, only MNF monoadducts have been purified.